Molecular Motion Inside an Adsorbed [5:1] Fullerene Hexaadduct Observed by Ultrafast Cyclic Voltammetry

被引：46

作者：

Fortgang, Philippe ^{[2
]}

Maisonhaute, Emmanuel ^{[1
]}

Amatore, Christian ^{[2
]}

Delavaux-Nicot, Beatrice ^{[3
]}

Iehl, Julien ^{[4
,5
]}

Nierengarten, Jean-Francois ^{[4
,5
]}

机构：

[1] Univ Paris 06, Lab Interfaces & Syst Electrochim UPR 15, F-75005 Paris, France

[2] Univ Paris 06, Ecole Normale Super, UMR CNRS PASTEUR 8640, F-75231 Paris 05, France

[3] Univ Toulouse UPS INP, Chim Coordinat Lab, CNRS, F-31077 Toulouse, France

[4] Univ Strasbourg, Lab Chim Mat Mol, F-67087 Strasbourg, France

[5] CNRS, UMR 7509, Ecole Europeenne Chim Polymeres & Mat, F-67087 Strasbourg, France

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2011年 / 50卷 / 10期

关键词：

cycloaddition; electrochemistry; ferrocenes; fullerenes; ultrafast cyclic voltammetry; INTERFACIAL ELECTRON-TRANSFER; TRANSFER RATE CONSTANTS; SELF-EXCHANGE; ADDITION PATTERN; KINETICS; C-60; FULLERODENDRIMERS; HEXAKISADDUCTS; DEPENDENCE; DENDRIMERS;

D O I：

10.1002/anie.201007289

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A rigid 3D scaffold in a 2D world! A mixed [5:1] fullerene hexaadduct that bears ten peripheral ferrocene redox subunits has been anchored onto a gold surface (see picture, green: iron, black: carbon, white: hydrogen, red: oxygen, blue: nitrogen). Ultrafast cyclic voltammetry investigations revealed that both intramolecular electron hopping and molecular motions influence the electron transfer from the ferrocene moieties to the electrode. (Figure Presented). © 2011 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：2364 / 2367

页数：4

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