Electrochemical Study of the Redox Properties of Levulinic Acid in Organic and Aqueous-Organic Solutions

被引：2
|
作者：
Burmakina, Galina, V [1 ]
Zimonin, Dmitry, V [1 ,2 ]
Rubaylo, Anatoly, I [1 ,2 ]
机构：
[1] Inst Chem & Chem Technol SB RAS, Krasnoyarsk, Russia
[2] Siberian Fed Univ, Krasnoyarsk, Russia
来源：
JOURNAL OF SIBERIAN FEDERAL UNIVERSITY-CHEMISTRY | 2021年 / 14卷 / 03期
关键词：
electrochemistry; redox properties; levulinic acid; gamma-valerolactone; GAMMA-VALEROLACTONE; TRANSFER HYDROGENATION; GENERATION; CONVERSION; CATALYSTS; EFFICIENT;
D O I：
10.17516/1998-2836-0246
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The redox properties of levulinic acid (LA) were studied by electrochemical methods in acetonitrile, a mixture of acetonitrile with water, ethanol, acetone, and dimethyl sulfoxide. It was shown that the irreversible two-electron reduction of LA under the studied conditions leads to the formation of gamma-valerolactone. This reduction potential depends on the solvent and shifted anodically by following order: dimethyl sulfoxide < acetonitrile <acetone <ethanol.
引用
收藏
页码：388 / 395
页数：8
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