(2,2′-Bipyridine-κ2N,N′)chlorido(1,4,7-trithiacyclononane-κ3S,S′,S")ruthenium(II) nitrate monohydrate

被引：1

作者：

Fernandes, Jose A. ^{[1
]}

Almeida Paz, Filipe A. ^{[1
]}

Mota, Maria Joao P. ^{[1
]}

Braga, Susana S. ^{[1
]}

Santos, Teresa M. ^{[1
]}

机构：

[1] Univ Aveiro, CICECO, Dept Chem, P-3810193 Aveiro, Portugal

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2010年 / 66卷

关键词：

STRUCTURAL-CHARACTERIZATION; CYCLODEXTRINS; COMPLEXES;

D O I：

10.1107/S1600536810046556

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the title compound, [RuCl(C10H8N2)(C6H12S3)]NO3 center dot H2O or [RuCl(bpy)([9]aneS(3))]NO3 center dot H2O, ([9]aneS(3) is 1,4,7-trithiacyclononane and bpy is 2,2'-bipyridine), the Ru-II cation has a slightly distorted octahedral environment composed of three facially coordinated S atoms from ([9]aneS(3)), two N atoms from bpy and a chloride anion. The nitrate counter-ion and the water molecule of crystallization are engaged in O-H center dot center dot center dot O hydrogen-bonding interactions, leading to a supramolecular chain running parallel to the c axis.

引用

页码：M1575 / U868

页数：12

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