Synthesis and characterization of a novel chloro-bridged bis cadmium(II) complex with bis(2-pyridylmethyl)amino-4-butyric acid

被引：29

作者：

Choi, KY ^{[1
]}

Jeon, YM ^{[1
]}

机构：

[1] Kongju Natl Univ, Dept Chem Educ, Kong Ju 314701, South Korea

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2003年 / 6卷 / 10期

关键词：

crystal structure; binuclear cadmium(II) complex; bis(2-pyridylmethyl)amino-4-butyric acid; bridged chlorides; octahedral geometry;

D O I：

10.1016/S1387-7003(03)00254-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of CdCl2 with bis(2-pyridylmethyl)amino-4-butyric acid (Hpmab) leads to the formation of binuclear complex [(Hpmab)(Cl)Cd-II(mu-Cl)(2)Cd-II(Cl)(Hpmab)] (1). Complex 1 can be regarded as two distorted octahedrons sharing the basal edge that contain the bridging chloro ligands, in each of which resides at a center of inversion. Cyclic voltammetry of I gives one oxidation and two reduced processes, (C) 2003 Elsevier B.V. All rights reserved.

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页码：1294 / 1296

页数：3

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