Electroactive self-assembled monolayers: Laviron's interaction model extended to non-random distribution of redox centers

被引：40

作者：

Aleveque, Olivier ^{[1
]}

Blanchard, Pierre-Yves ^{[1
]}

Gautier, Christelle ^{[1
]}

Dias, Marylene ^{[1
]}

Breton, Tony ^{[1
]}

Levillain, Eric ^{[1
]}

机构：

[1] Univ Angers, Lab CIMA, CNRS, F-49045 Angers, France

来源：

ELECTROCHEMISTRY COMMUNICATIONS | 2010年 / 12卷 / 11期

关键词：

Tempo; Self-assembled monolayers; Cyclic voltammetry; Interaction model; POTENTIAL SWEEP VOLTAMMETRY; MODIFIED ELECTRODES; ADSORBED MOLECULES; SURFACE; ADSORPTION;

D O I：

10.1016/j.elecom.2010.07.039

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

The Laviron's interaction model, dedicated to randomly distributed electroactive adsorbed species, was extended to a non-random distribution in order to extract the current-voltage characteristics from any surface distribution of electroactive centers on self-assembled monolayer (SAM). Confronted to electrochemical behaviour of nitroxyl radical SAMs, the agreement observed between theory and experiments provides evidence of a distribution independence of the interaction parameters. (C) 2010 Elsevier B.V. All rights reserved.

引用

页码：1462 / 1466

页数：5

共 14 条

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