Characteristics of thermoplastic sugar palm Starch/Agar blend: Thermal, tensile, and physical properties

被引:89
作者
Jumaidin, R. [1 ,4 ]
Sapuan, S. M. [1 ,3 ]
Jawaid, M. [4 ]
Ishak, M. R. [2 ]
Sahari, J. [5 ]
机构
[1] Univ Putra Malaysia, Dept Mech & Mfg Engn, Upm Serdang 43400, Selangor, Malaysia
[2] Univ Putra Malaysia, Dept Aerosp Engn, Upm Serdang 43400, Selangor, Malaysia
[3] Univ Putra Malaysia, Inst Trop Forestry & Forest Prod INTROP, Lab Biocomposite Technol, Upm Serdang 43400, Selangor, Malaysia
[4] Univ Teknikal Malaysia, Fac Mech Engn, Dept Mat & Struct, Durian Tunggal 76100, Melaka, Malaysia
[5] Univ Malaysia Sabah, Fac Sci & Nat Resources, Kota Kinabalu 88400, Saga, Malaysia
关键词
Thermoplastic starch; Starch; Agar; TREE ARENGA-PINNATA; CASSAVA STARCH; PHYSICOCHEMICAL PROPERTIES; PLASTICIZED STARCH; NANOCOMPOSITE FILM; BARRIER PROPERTIES; AGAR FILMS; COMPOSITES; CELLULOSE; FIBERS;
D O I
10.1016/j.ijbiomac.2016.05.028
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
The aim of this work is to study the behavior of biodegradable sugar palm starch (SPS) based thermoplastic containing agar in the range of 10-40 wt%. The thermoplastics were melt-mixed and then hot pressed at 140 degrees C for 10 min. SEM investigation showed good miscibility between SPS and agar. FT-IR analysis confirmed that SPS and agar were compatible and inter-molecular hydrogen bonds existed between them. Incorporation of agar increased the thermoplastic starch tensile properties (Young's modulus and tensile strength). The thermal stability and moisture uptake increased with increasing agar content. The present work shows that starch-based thermoplastics with 30 wt% agar content have the highest tensile strength. Higher content of agar (40 wt%) resulted to more rough cleavage fracture and slight decrease in the tensile strength. In conclusion, the addition of agar improved the thermal and tensile properties of thermoplastic SPS which widened the potential application of this eco-friendly material. The most promising applications for this eco-friendly material are short-life products such as packaging, container, tray, etc. (C) 2016 Elsevier B.V. All rights reserved.
引用
收藏
页码:575 / 581
页数:7
相关论文
共 40 条
[1]   Preparation and characterization agar-based nanocomposite film reinforced by nanocrystalline cellulose [J].
Atef, Maryam ;
Rezaei, Masoud ;
Behrooz, Rabi .
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES, 2014, 70 :537-544
[2]   Shape-memory starch for resorbable biomedical devices [J].
Beilvert, A. ;
Chaubet, F. ;
Chaunier, L. ;
Guilois, S. ;
Pavon-Djavid, G. ;
Letourneur, D. ;
Meddahi-Pelle, A. ;
Lourdin, D. .
CARBOHYDRATE POLYMERS, 2014, 99 :242-248
[3]   Physicochemical properties of granular and non-granular cationic starches prepared under ultra high pressure [J].
Chang, Yoon-Je ;
Choi, Hyun-Wook ;
Kim, Hyun-Seok ;
Lee, Hyungjae ;
Kim, Wooki ;
Kim, Dae-Ok ;
Kim, Byung-Yong ;
Baik, Moo-Yeol .
CARBOHYDRATE POLYMERS, 2014, 99 :385-393
[4]  
Edhirej A., 2015, POLYM COMPOSITE, V16, P1, DOI DOI 10.1002/PC
[5]   The preparation and characterisation of a series of chemically modified potato starches [J].
Fang, JM ;
Fowler, PA ;
Tomkinson, J ;
Hill, CAS .
CARBOHYDRATE POLYMERS, 2002, 47 (03) :245-252
[6]   Degradation of agar films in a humid tropical climate:: Thermal, mechanical morphological and structural changes [J].
Freile-Pelegrin, Y. ;
Madera-Santana, T. ;
Robledo, D. ;
Veleva, L. ;
Quintana, P. ;
Azamar, J. A. .
POLYMER DEGRADATION AND STABILITY, 2007, 92 (02) :244-252
[7]   Release of active compounds from agar and agar-gelatin films with green tea extract [J].
Gimenez, B. ;
Lopez de Lacey, A. ;
Perez-Santin, E. ;
Lopez-Caballero, M. E. ;
Montero, P. .
FOOD HYDROCOLLOIDS, 2013, 30 (01) :264-271
[8]   Bionanocomposites of thermoplastic starch and cellulose nanofibers manufactured using twin-screw extrusion [J].
Hietala, Maiju ;
Mathew, Aji P. ;
Oksman, Kristiina .
EUROPEAN POLYMER JOURNAL, 2013, 49 (04) :950-956
[9]   Characteristics of starch-based biodegradable composites reinforced with date palm and flax fibers [J].
Ibrahim, Hamdy ;
Farag, Mahmoud ;
Megahed, Hassan ;
Mehanny, Sherif .
CARBOHYDRATE POLYMERS, 2014, 101 :11-19
[10]   Sugar palm (Arenga pinnata): Its fibres, polymers and composites [J].
Ishak, M. R. ;
Sapuan, S. M. ;
Leman, Z. ;
Rahman, M. Z. A. ;
Anwar, U. M. K. ;
Siregar, J. P. .
CARBOHYDRATE POLYMERS, 2013, 91 (02) :699-710