Spectroscopic properties of microporous layered tin sulfide materials

被引：26
作者：
Jiang, T
Ozin, GA [1 ]
Bedard, RL
机构：
[1] Univ Toronto, Dept Chem, Mat Chem Res Grp, Toronto, ON M5S 3H6, Canada
[2] Universal Oil Prod, Des Plaines, IL 60017 USA
来源：
JOURNAL OF MATERIALS CHEMISTRY | 1998年 / 8卷 / 07期
关键词：
D O I：
10.1039/a801602j
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Sn-119 solid state nuclear magnetic resonance, Sn-119 Mossbauer, Fourier transform Raman and variable temperature single crystal W-VIS absorption, emission and excitation spectra of some archetypal microporous layered tin sulfides, denoted (Et4N)(2)Sn3S7 (TEA-SnS-1), (C6H12N2H)(2)Sn3S7 (DABCOH-SnS-1), (NH4)(0.5)(Et4N)(1-5)Sn3S7 (ATEA-SnS-1) and (Pr4N)(2)Sn4S9 (TPA-SnS-3), are reported. The combined spectroscopic results provide a rather comprehensive picture of structure-property relations for this novel class of solids, which have the unusual ability of being able to behave as both molecular sieve and intercalation materials to a range of guests.
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页码：1641 / 1648
页数：8
相关论文
共 30 条
  • [1] Effect of microgravity on the crystallization of a self-assembling layered material
    Ahari, H
    Bedard, RL
    Bowes, CL
    Coombs, N
    Dag, O
    Jiang, T
    Ozin, GA
    Petrov, S
    Sokolov, I
    Verma, A
    Vovk, G
    Young, D
    [J]. NATURE, 1997, 388 (6645) : 857 - 860
  • [2] NANOPOROUS TIN(IV) CHALCOGENIDES - FLEXIBLE OPEN-FRAMEWORK NANOMATERIALS FOR CHEMICAL SENSING
    AHARI, H
    BOWES, CL
    JIANG, T
    LOUGH, A
    OZIN, GA
    BEDARD, FL
    PETROV, S
    YOUNG, D
    [J]. ADVANCED MATERIALS, 1995, 7 (04) : 375 - 378
  • [3] Dimensional reduction in II-VI materials: A(2)Cd(3)Q(4) (A=K, Q=S, Se, Te; A=Rb, Q=S, Se), novel ternary low-dimensional cadmium chalcogenides produced by incorporation of A(2)Q in CdQ
    Axtell, EA
    Liao, JH
    Pikramenou, Z
    Kanatzidis, MG
    [J]. CHEMISTRY-A EUROPEAN JOURNAL, 1996, 2 (06) : 656 - 666
  • [4] BEDARD RL, 1997, Patent No. 5594263
  • [5] ULTRAVIOLET PROPERTIES AND BAND-STRUCTURE OF SNS2, SNSE2, CDI2, PBI2, BII3 AND BIOI CRYSTALS
    BORDAS, J
    ROBERTSON, J
    JAKOBSSON, A
    [J]. JOURNAL OF PHYSICS C-SOLID STATE PHYSICS, 1978, 11 (12): : 2607 - 2621
  • [6] Microporous layered tin sulfide, SnS-1: molecular sieve or intercalant?
    Bowes, CL
    Petrov, S
    Vovk, G
    Young, D
    Ozin, GA
    Bedard, RL
    [J]. JOURNAL OF MATERIALS CHEMISTRY, 1998, 8 (03) : 711 - 720
  • [7] Self-assembling frameworks: Beyond microporous oxides
    Bowes, CL
    Ozin, GA
    [J]. ADVANCED MATERIALS, 1996, 8 (01) : 13 - +
  • [8] BULLOCK JI, 1972, J CHEM SOC DA, P1844
  • [9] Does microgravity influence self-assembly
    Dag, O
    Ahari, H
    Coombs, N
    Jiang, T
    ArocaOuellette, PP
    Petrov, S
    Sokolov, I
    Verma, A
    Vovk, G
    Young, D
    Ozin, GA
    Reber, C
    Pelletier, Y
    Bedard, RL
    [J]. ADVANCED MATERIALS, 1997, 9 (15) : 1133 - &
  • [10] IMAGING THE SURFACES OF NANOPOROUS SEMICONDUCTORS BY ATOMIC-FORCE MICROSCOPY
    ENZEL, P
    HENDERSON, GS
    OZIN, GA
    BEDARD, RL
    [J]. ADVANCED MATERIALS, 1995, 7 (01) : 64 - 68
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