A Monomeric Dilithio Methandiide with a Distorted trans-Planar Four-Coordinate Carbon

被引：44

作者：

Cooper, Oliver J. ^{[1
]}

Wooles, Ashley J. ^{[1
]}

McMaster, Jonathan ^{[1
]}

Lewis, William ^{[1
]}

Blake, Alexander J. ^{[1
]}

Liddle, Stephen T. ^{[1
]}

机构：

[1] Univ Nottingham, Sch Chem, Nottingham NG7 2RD, England

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 32期

基金：

英国工程与自然科学研究理事会;

关键词：

lithium; methandiide; N; P ligands; planar four-coordinate carbon; structure elucidation; TETRACOORDINATE CARBON; CRYSTAL-STRUCTURE; STRUCTURAL-CHARACTERIZATION; CHEMISTRY; HEXAPHENYLCARBODIPHOSPHORANE; TRIBOLUMINESCENCE; POLYMORPHS; COMPLEXES; RADII;

D O I：

10.1002/anie.201002483

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

It's plain to see: A monomeric dilithio methandiide features a distorted transplanar four-coordinate carbon atom. The nature of this compound as established by an X-ray diffraction study (see picture: C black, N blue, P magenta, Li red) and supported by calculations. (Figure Presented) © 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：5570 / 5573

页数：4

共 36 条

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Russian Journal of Inorganic Chemistry, 2015, 60 : 1481 - 1486
[32] cis- and trans-planar four-coordinated palladium(II) azo-5-pyrazolone (thione) complexes with N2O2- and N2S2-ligand environment: Synthesis and structure
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Uraev, A. I.
Lysenko, K. A.
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[33] Monomeric, Four-Coordinate Group 4 Metal Complexes with Chelating Bis(tert-butylamido)cyclodisilazane Ligands: Syntheses and Molecular Structures of {(MeSiNtBu)2-(NtBu)2}MCl2 and {(MeSiNtBu)2(NtBu)2}-MMe2, M = Zr, Hf
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[34] Diamminesilver(I) bis(2-amino-5-nitrobenzoato-κ2O1,O1′)silver(I): a two-dimensional supramolecular sheet with a short intersheet distance containing a rare four-coordinate planar silver(I) centre
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[35] Monomeric, four-coordinate group 4 metal complexes with chelating bis(tert-butylamido)cyclodisilazane ligands: Syntheses and molecular structures of {((MeSiNBu)-Bu-t)(2)((NBu)-Bu-t)(2)}MCl2 and {((MeSiNBu)-Bu-t)(2)((NBu)-Bu-t)(2)}MMe2, M=Zr, Hf
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[36] Oxidative addition to a monomeric stannylene to give four-coordinate tin compounds containing the bulky bidentate ligand C(SiMe3)2SiMe2CH2CH2Me2Si(Me3Si)2C.: Crystal structures of CH2Me2Si(Me3Si)2CSnC(SiMe3)2SiMe2CH2, CH2Me2Si(Me3Si)2CSnMe(OCOCF3)C(SiMe3)2SiMe2CH2, and (CF3COO)2MeSnC(SiMe3)2SiMe2CH2CH2Me2Si(Me3Si)2CSnMe(OCOCF3)2
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Patel, D
Smith, JD
Zhang, SB
ORGANOMETALLICS, 2000, 19 (01) : 49 - 53

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