A Monomeric Dilithio Methandiide with a Distorted trans-Planar Four-Coordinate Carbon

被引：44

作者：

Cooper, Oliver J. ^{[1
]}

Wooles, Ashley J. ^{[1
]}

McMaster, Jonathan ^{[1
]}

Lewis, William ^{[1
]}

Blake, Alexander J. ^{[1
]}

Liddle, Stephen T. ^{[1
]}

机构：

[1] Univ Nottingham, Sch Chem, Nottingham NG7 2RD, England

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 32期

基金：

英国工程与自然科学研究理事会;

关键词：

lithium; methandiide; N; P ligands; planar four-coordinate carbon; structure elucidation; TETRACOORDINATE CARBON; CRYSTAL-STRUCTURE; STRUCTURAL-CHARACTERIZATION; CHEMISTRY; HEXAPHENYLCARBODIPHOSPHORANE; TRIBOLUMINESCENCE; POLYMORPHS; COMPLEXES; RADII;

D O I：

10.1002/anie.201002483

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

It's plain to see: A monomeric dilithio methandiide features a distorted transplanar four-coordinate carbon atom. The nature of this compound as established by an X-ray diffraction study (see picture: C black, N blue, P magenta, Li red) and supported by calculations. (Figure Presented) © 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：5570 / 5573

页数：4

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