Palladium(0)-Catalyzed Intermolecular Cascade Dearomatization Reaction of β-Naphthol Derivatives with Propargyl Carbonates

被引：36
作者：
Ding, Lu [2 ]
You, Shu-Li [1 ,2 ]
机构：
[1] Univ Chinese Acad Sci, Chinese Acad Sci, State Key Lab Organometall Chem, Ctr Excellence Mol Synth,Shanghai Inst Organ Chem, 345 Lingling Lu, Shanghai 200032, Peoples R China
[2] ShanghaiTech Univ, Sch Phys Sci & Technol, 100 Haike Rd, Shanghai 201210, Peoples R China
来源：
ORGANIC LETTERS | 2018年 / 20卷 / 19期
基金：
国家重点研发计划;
关键词：
CATALYTIC ASYMMETRIC DEAROMATIZATION; INTRAMOLECULAR DEAROMATIZATION; ALLYLIC ETHERIFICATION; NATURAL-PRODUCTS; ARYLATIVE DEAROMATIZATION; PHENOL DEAROMATIZATION; SPIROCYCLIC COMPOUNDS; QUATERNARY CENTERS; RECENT PROGRESS; O-ALLYLATION;
D O I：
10.1021/acs.orglett.8b02681
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A Pd(0)-catalyzed intermolecular cascade dearomatization reaction of beta-naphthol derivatives with propargyl carbonates was described. In the presence of a Pd complex derived from Pd(2)dba(3) and rac-BINAP, various spironaphthalenones were obtained in excellent yields (up to 95%) and with high chemoselectivity (C/O > 20:1) in most cases.
引用
收藏
页码：6206 / 6210
页数：5
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