Order parameters in the diffusion of rods through two- and three-dimensional fixed scatterers

被引:0
|
作者
Mahala, Benjamin D. [1 ]
Hernandez, Rigoberto [1 ]
机构
[1] Johns Hopkins Univ, Dept Chem, Charles & 34Th St, Baltimore, MD 21218 USA
基金
美国国家科学基金会;
关键词
LORENTZ GAS; THICK NEEDLE; DYNAMICS; DIMERS; DIVERGENCES; MECHANISMS; EXPANSION; BEHAVIOR; DENSITY;
D O I
10.1103/PhysRevE.98.042607
中图分类号
O35 [流体力学]; O53 [等离子体物理学];
学科分类号
070204 ; 080103 ; 080704 ;
摘要
Characteristic diffusion in a Lorentz gas system and its extensions are typically described through a scale-free order parameter. The relative validity of possible order parameters for the diffusion of a thick tracer rod through spherical scatterers in two and three dimensions as a function of the rod length L and scatterer density rho has been examined by simulation. We find that the often-used two-dimensional order parameter, rho L-2, is accurate. However, its naive generalization to three dimensions, changing the exponent according to dimensionality, does not fit the observed results. A revised order parameter can be generated through a theory based on the behavior of the mean-free path of the tracer. We find that this generalized order parameter captures the multidimensional diffusive behavior.
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页数:8
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