The effect of aromatic-aromatic interactions on the crystallization of helical nickel(II) complexes

被引：8

作者：

Kawamoto, T ^{[1
]}

Kushi, Y ^{[1
]}

机构：

[1] Osaka Univ, Grad Sch Sci, Dept Chem, Toyonaka, Osaka 5600043, Japan

来源：

INORGANICA CHIMICA ACTA | 1998年 / 282卷 / 01期

关键词：

crystal structures; nickel complexes; N; S-ligand complexes;

D O I：

10.1016/S0020-1693(98)00195-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Five monometallic helical nickel(II) complexes, with various substituents on the pendant arms, were prepared. The crystal structures of three complexes consist of alternating right- and left-handed helical complexes, with intermolecular face-to-face interactions. On the other hand, the other two complexes crystallize in right-handed or left-handed molecules alone, with intermolecular edge-to-face interactions. This behaviour can be correlated with the electron-releasing properties of the substituents on the pendant arms. (C) 1998 Elsevier Science S.A. All rights reserved.

引用

页码：71 / 75

页数：5

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