Structural interconversion between a chain polymer and a two-dimensional network accompanied by tunable magnetic properties

被引：19

作者：

Chen, Chao ^{[1
,2
]}

Sun, Jian-Ke ^{[1
,2
]}

Li, Wei ^{[1
,2
]}

Chen, Chang-Neng ^{[1
]}

Zhang, Jie ^{[1
]}

机构：

[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China

[2] Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 23期

关键词：

SINGLE-CRYSTAL TRANSFORMATION; COORDINATION POLYMER; COPPER(II) COMPLEXES; SPIN-CROSSOVER; ZIGZAG CHAIN; FRAMEWORK; LIGAND; STATE;

D O I：

10.1039/c0cc05763k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of 2-hydroxypyrimidine-4,6-dicarboxylic acid (H(3)hpdc) with CuCl(2) under different temperatures gives a chain-like compound [Cu(2)(hpdc)(OH)(H(2)O)(4)]center dot H(2)O and a layer-like compound [Cu(2)(hpdc)(OH)(H(2)O)], which exhibit structural interconversion and tunable magnetic properties upon dehydration and hydration.

引用

页码：6683 / 6685

页数：3

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