Mode of boron solubility in ferrous alloys

被引:14
作者
Calos, NJ [1 ]
Graham, E
Cousens, DR
Christodoulou, P
Kennard, CHL
Bekessy, LK
Parker, SF
机构
[1] Univ Queensland, Dept Chem, Brisbane, Qld 4072, Australia
[2] Univ Queensland, Dept Earth Sci, Brisbane, Qld 4072, Australia
[3] CSIRO, Mfg Sci & Technol, Kenmore, Qld 4096, Australia
[4] Univ Queensland, Ctr Microscopy & Microanal, Brisbane, Qld 4072, Australia
[5] Univ Queensland, Dept Min Minerals & Mat Engn, Brisbane, Qld 4072, Australia
[6] Rutherford Appleton Lab, ISIS Facil, Didcot OX11 0QX, Oxon, England
关键词
boron; solubility; steel; inelastic neutron scattering; phonon dispersion; X-ray diffraction; neutron diffraction; rietveld analysis; dynamic mechanical analysis; internal friction;
D O I
10.2320/matertrans.42.496
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
X-ray and neutron diffractometry and inelastic neutron scattering studies on a set of cast ferritic iron-chromium alloys containing boron indicate that the dissolved boron is present interstitially rather than substitutionally within the alpha -Fe,Cr matrix. Inelastic neutron scattering spectra of the alloys may be interpreted in terms of the phonon dispersion curves for alpha -Fe. These spectra show small shifts in the frequencies of particular phonons, indicative of lattice disruption by the presence of interstitial atoms. These results were subsequently confirmed by internal friction measurements.
引用
收藏
页码:496 / 501
页数:6
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