Hexakis(pyridine N-oxide-κO) iron(II) tetraphenylborate

被引:3
作者
Crossland, Justin L. [1 ]
Zakharov, Lev N. [1 ]
Tyler, David R. [1 ]
机构
[1] Univ Oregon 1253, Dept Chem, Eugene, OR 97403 USA
关键词
single-crystal X-ray study; T=173 K; Mean sigma(C-C)=0.004 angstrom; R factor=0.065; wR factor=0.122; data-to-parameter ratio=16.7;
D O I
10.1107/S1600536807013931
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The FeII cation in [Fe(C5H5NO)(6)](C24H20B)(2) has a distorted octahedral coordination with the Fe-O distances in the range 2.085 (2)-2.148 (2) angstrom. In the crystal structure the [Fe(C5H5NO)(6)](2+) cations and the BPh4- anions are involved in a pi-pi and six C-H center dot center dot center dot pi intermolecular interactions between pyridine and the phenyl rings of the counter-ions.
引用
收藏
页码:M1196 / M1197
页数:2
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