Synthesis and luminescent properties of functionalized polynorbornenes with boron-containing fragments in side chains

被引：0

作者：

Rozhkov, A. V. ^{[1
]}

Basova, G. V. ^{[1
]}

Korshunov, A. O. ^{[1
,2
]}

Bochkarev, L. N. ^{[1
,2
]}

Glukhova, T. A. ^{[1
]}

Il'ichev, V. A. ^{[1
,2
]}

机构：

[1] Russian Acad Sci, GA Razuvaev Inst Organometall Chem, 49 Ul Tropinina, Nizhnii Novgorod 603950, Russia

[2] NI Lobachevsky Nizhny Novgorod State Univ, 23 Prosp Gagarina, Nizhnii Novgorod 603950, Russia

来源：

RUSSIAN CHEMICAL BULLETIN | 2015年 / 64卷 / 08期

基金：

俄罗斯基础研究基金会;

关键词：

luminescent polymers; metathesis polymerization; boron; carbazole; photoluminescence; electroluminescence; LIGHT-EMITTING-DIODES; ELECTROPHOSPHORESCENT DEVICES; ELECTROLUMINESCENT PROPERTIES; ORGANOBORON COMPOUNDS; METATHESIS; FLUORESCENCE; COPOLYMERS; EMISSION; LIGANDS; OLEDS;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

New norbornene monomer, viz., 5-[(bicyclo[2.2.1]hept-5-en-2-ylmethoxy)methyl]-8-[(dimesitylboryl)oxy]quinoline (1), was synthesized. The copolymers based on monomer 1 and carbazole-containing norbornene derivatives were synthesized by ring-opening metathesis polymerization. The photoluminescent (PL) and electroluminescent (EL) properties of the synthesized polymeric products were studied. The copolymers revealed the green EL with a maximum luminance of 146 cd m(-2). The dependences between the PL and EL efficiencies of the polymers and their structures were determined.

引用

页码：1949 / 1954

页数：6

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