Synthesis and luminescent properties of functionalized polynorbornenes with boron-containing fragments in side chains

被引：0
作者：
Rozhkov, A. V. [1 ]
Basova, G. V. [1 ]
Korshunov, A. O. [1 ,2 ]
Bochkarev, L. N. [1 ,2 ]
Glukhova, T. A. [1 ]
Il'ichev, V. A. [1 ,2 ]
机构：
[1] Russian Acad Sci, GA Razuvaev Inst Organometall Chem, 49 Ul Tropinina, Nizhnii Novgorod 603950, Russia
[2] NI Lobachevsky Nizhny Novgorod State Univ, 23 Prosp Gagarina, Nizhnii Novgorod 603950, Russia
来源：
RUSSIAN CHEMICAL BULLETIN | 2015年 / 64卷 / 08期
基金：
俄罗斯基础研究基金会;
关键词：
luminescent polymers; metathesis polymerization; boron; carbazole; photoluminescence; electroluminescence; LIGHT-EMITTING-DIODES; ELECTROPHOSPHORESCENT DEVICES; ELECTROLUMINESCENT PROPERTIES; ORGANOBORON COMPOUNDS; METATHESIS; FLUORESCENCE; COPOLYMERS; EMISSION; LIGANDS; OLEDS;
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
New norbornene monomer, viz., 5-[(bicyclo[2.2.1]hept-5-en-2-ylmethoxy)methyl]-8-[(dimesitylboryl)oxy]quinoline (1), was synthesized. The copolymers based on monomer 1 and carbazole-containing norbornene derivatives were synthesized by ring-opening metathesis polymerization. The photoluminescent (PL) and electroluminescent (EL) properties of the synthesized polymeric products were studied. The copolymers revealed the green EL with a maximum luminance of 146 cd m(-2). The dependences between the PL and EL efficiencies of the polymers and their structures were determined.
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页码：1949 / 1954
页数：6
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