N-tosylaziridine, a new substrate for chemical fixation of carbon dioxide via ring expansion reaction under atmospheric pressure

被引：63

作者：

Sudo, A

Morioka, Y

Sanda, F

Endo, T ^{[1
]}

机构：

[1] Yamagata Univ, Fac Engn, Dept Polymer Sci & Engn, Yamagata 9928510, Japan

[2] Kinki Univ, Mol Engn Inst, Fukuoka 8208555, Japan

[3] Tokyo Inst Technol, Chem Resources Lab, Midori Ku, Yokohama, Kanagawa 2268503, Japan

[4] Kyoto Univ, Grad Sch Engn, Dept Polymer Chem, Sakyo Ku, Kyoto 6068501, Japan

来源：

TETRAHEDRON LETTERS | 2004年 / 45卷 / 07期

关键词：

aziridine; cycloaddition; carbon dioxide; atmospheric pressure; carbon disulfide;

D O I：

10.1016/j.tetlet.2003.12.052

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Al-Tosvlaziridine was found to be a useful substrate for cycloaddition reaction with carbon dioxide. The reaction was successfully catalyzed by lithium bromide under atmospheric pressure to give the corresponding five-membered cyclic urethane, N-tosyl-1,3-oxazolidin-2-one. selectively. It was found that electron-donating nature of the substituent at 2-position of N-tosylaziridine accelerated the reaction, and this tendency allowed Lis to estimate the reaction mechanism. (C) 2003 Elsevier Ltd. All rights reserved.

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页码：1363 / 1365

页数：3

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