Iodine Monochloride (ICl) as a Highly Efficient, Green Oxidant for the Oxidation of Alcohols to Corresponding Carbonyl Compounds

被引：10

作者：

Wei, Peng ^{[1
,2
]}

Zhang, Datong ^{[1
]}

Gao, Zhigang ^{[1
,2
]}

Cai, Wenqing ^{[2
]}

Xu, Weiren ^{[2
]}

Tang, Lida ^{[2
]}

Zhao, Guilong ^{[1
,2
]}

机构：

[1] Qilu Univ Technol, Sch Chem & Pharmaceut Engn, Jinan 250353, Peoples R China

[2] Tianjin Inst Pharmaceut Res, Tianjin Key Lab Mol Design & Drug Discovery, Tianjin 300193, Peoples R China

来源：

SYNTHETIC COMMUNICATIONS | 2015年 / 45卷 / 12期

基金：

中国国家自然科学基金;

关键词：

Aldose hemiacetal; green oxidant; iodine monochloride; lactonization; synthesis; BIOLOGICAL EVALUATION; INHIBITORS; GLUCOSIDE; DISCOVERY; BEHAVIOR;

D O I：

10.1080/00397911.2015.1005630

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Iodine monochloride (ICl) was discovered to be a highly efficient, green oxidant, which can oxidize aldose hemiacetals, diarylmethanols, arylalkylmethanols, anddialkylmethanols to the corresponding aldose lactones, diarylmethanones, arylalkylmethanones, and dialkylmethanones, respectively, in high yields. ICl as a green, metal-free oxidant is characterized by mild reaction condition, short reaction time, good yield, and broad scope.

引用

页码：1457 / 1470

页数：14

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