Synthesis and Magnetic Properties of Dimethylmethylenebis(iminonitroxide) Diradical

被引：10

作者：

Suzuki, Shuichi ^{[1
]}

Itoh, Noriyuki ^{[1
]}

Furuichi, Kimiaki ^{[1
]}

Kozaki, Masatoshi ^{[1
]}

Shiomi, Daisuke ^{[1
]}

Sato, Kazunobu ^{[1
]}

Takui, Takeji ^{[1
]}

Ohi, Hiromi ^{[1
]}

Itoh, Shinobu ^{[1
]}

Okada, Keiji ^{[1
]}

机构：

[1] Osaka City Univ, Dept Chemisny, Grad Sch Sci, Sumiyoshi Ku, Osaka 5588585, Japan

来源：

CHEMISTRY LETTERS | 2011年 / 40卷 / 01期

关键词：

EXCHANGE INTERACTION;

D O I：

10.1246/cl.2011.22

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Dimethylmethylenebis(iminonitroxide) diradical 1 was prepared from 3-hydroxy-2,2-dimethylpropanal in five steps. The structure, ESR spectrum, and magnetic properties are reported: 1 exhibited an antiferromagnetic interaction of J/k(B) = -72 K (H = -2JS(1).S-2).

引用

页码：22 / 24

页数：3

共 14 条

[1]

[Anonymous], SPART 08

[2] ANOMALOUS PARAMAGNETISM OF COPPER ACETATE [J].

BLEANEY, B ;

BOWERS, KD .

PROCEEDINGS OF THE ROYAL SOCIETY OF LONDON SERIES A-MATHEMATICAL AND PHYSICAL SCIENCES, 1952, 214 (1119) :451-465

[3]

Frisch M. J., 2016, Gaussian 03 Revision B.03

[4]

Hirel C, 2001, CHEM-EUR J, V7, P2007, DOI 10.1002/1521-3765(20010504)7:9<2007::AID-CHEM2007>3.0.CO

[5]

2-7

[6]

Lahti PM, 1996, ACS SYM SER, V644, P218

[7] A New Ferrimagnet Based on a Radical-Substituted Radical Cation Salt [J].

Masuda, Yuki ;

Kuratsu, Masato ;

Suzuki, Shuichi ;

Kozaki, Masatoshi ;

Shiomi, Daisuke ;

Sato, Kazunobu ;

Takui, Takeji ;

Hosokoshi, Yuko ;

Lan, Xiao-Zheng ;

Miyazaki, Yuji ;

Inaba, Akira ;

Okada, Keiji .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (13) :4670-4673

[8] Exchange interaction of bispyridinyl diradicals linked by σ-frames [J].

Matsumoto, K ;

Oda, M ;

Kozaki, M ;

Sato, K ;

Takui, T ;

Okada, K .

TETRAHEDRON LETTERS, 1998, 39 (35) :6307-6310

[9]

Shultz DA, 1999, MAGNETIC PROPERTIES OF ORGANIC MATERIALS, P103

[10] Exchange interaction of 5,5′-(m- and p-phenylene)bis(10-phenyl-5,10-dihydrophenazine) dications and related analogues [J].

Terada, E ;

Okamoto, T ;

Kozaki, M ;

Masaki, ME ;

Shiomi, D ;

Sato, K ;

Takui, T ;

Okada, K .

JOURNAL OF ORGANIC CHEMISTRY, 2005, 70 (24) :10073-10081

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