Light energy conversion device for photocatalyst 2 0%WO3-TiO2 with oxygen vacancies for water splitting

被引:1
作者
Tong Hai-xia [1 ]
Chen Qi-yuan [2 ]
Hu Hui-ping [2 ]
Yin Zhou-lan [2 ]
机构
[1] Changsha Univ Sci & Technol, Inst Chem & Biol Engn, Changsha 410076, Hunan, Peoples R China
[2] Cent S Univ, Sch Chem & Chem Engn, Changsha 410083, Peoples R China
来源
JOURNAL OF CENTRAL SOUTH UNIVERSITY OF TECHNOLOGY | 2010年 / 17卷 / 05期
关键词
light energy conversion device photocatalytic activity; O-2; evolution; oxygen vacancy; photo splitting water; O-2; IRRADIATION; H-2; CATALYSTS; BEHAVIOR; OXIDE;
D O I
10.1007/s11771-010-0581-6
中图分类号
TF [冶金工业];
学科分类号
0806 ;
摘要
Using carbon felt, polytetrafluoroethylene latex and powder catalyst to assembly a light energy conversion device, the photocatalytic activity of catalyst 2 0%WO3-TiO2 (2%WO3 compounding TiO2) with oxygen vacancies was studied through the water splitting for O-2 evolution, using a high pressure mercury lamp as the light source and Fe3+ as the electron acceptor in two different devices an ordinary photolysis device with catalyst powder suspending through a magnetic stirrer and a self assembly light energy conversion device The results show that after 12 h irradiation, the photocatalytic activity of 2 0%WO3-TiO2 with oxygen vacancies in the self-assembly light energy conversion device is higher than that of the ordinary photolysis device, and the amount of oxygen evolution is about 12 and 9 mmol/L respectively in these two devices After 12 h the rates of O-2 evolution are slow in each device and the photocatalyst almost loses the photoactivity in the ordinary photolysis device So compared with the ordinary photocatalytic device, the rate of oxygen evolution and the life time of the catalyst are improved in the self-assembly light energy conversion device
引用
收藏
页码:943 / 946
页数:4
相关论文
共 16 条
[1]   Significant effect of iodide addition on water splitting into H2 and O2 over Pt-loaded TiO2 photocatalyst:: suppression of backward reaction [J].
Abe, R ;
Sayama, K ;
Arakawa, H .
CHEMICAL PHYSICS LETTERS, 2003, 371 (3-4) :360-364
[2]   Cerium dioxide as a photocatalyst for water decomposition to O2 in the presence of Ce4+aq and Fe3+aq species [J].
Bamwenda, GR ;
Arakawa, H .
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2000, 161 (1-2) :105-113
[3]   The photocatalytic oxidation of water to O2 over pure CeO2, WO3, and TiO2 using Fe3+ and Ce4+ as electron acceptors [J].
Bamwenda, GR ;
Uesigi, T ;
Abe, Y ;
Sayama, K ;
Arakawa, H .
APPLIED CATALYSIS A-GENERAL, 2001, 205 (1-2) :117-128
[4]   Synthesis of visible light responsive ultrafine K4Ce2Nb10O30 by a stearic acid method [J].
Chen Haiqun ;
Zhu Junwu ;
Ma Junxing ;
Pang Kai ;
Sun Xiaoqiang .
JOURNAL OF RARE EARTHS, 2009, 27 (05) :811-814
[5]  
CHEN QY, 2005, PRACTICAL HYDROGEN P, P379
[6]  
HUANG XW, 1993, PRINCIPLE NONFERROUS, P30
[7]  
LI XY, 2001, MOL CATALYSIS, V15, P72
[8]  
MASAAKI K, 2007, CATAL TODAY, V120, P133
[9]  
MASAYA M, 2008, CATAL TODAY, V132, P159
[10]   Preparation, characterization and photocatalytic behavior of WO3TiO2/Nb2O5 catalysts [J].
Tong Hai-xia ;
Chen Qi-yuan ;
Hu Hui-ping ;
Yin Zhou-lan ;
Li Jie ;
Zhou Jian-liang .
JOURNAL OF CENTRAL SOUTH UNIVERSITY OF TECHNOLOGY, 2007, 14 (06) :788-792