Fabrication of green and orange photoluminescent, undoped ZnO films using spray pyrolysis

被引:1034
作者
Studenikin, SA [1 ]
Golego, N
Cocivera, M
机构
[1] Univ Guelph, Guelph Waterloo Ctr Grad Work Chem, Guelph, ON N1G 2W1, Canada
[2] Russian Acad Sci, Inst Semicond Phys, Siberian Branch, Novosibirsk 630090, Russia
关键词
D O I
10.1063/1.368295
中图分类号
O59 [应用物理学];
学科分类号
摘要
Photoluminescent, undoped ZnO films have been fabricated using spray pyrolysis of zinc nitrate solution. The luminescent films had a polycrystalline hexagonal wurtzite type structure with no preferred orientation. Photoluminescence intensity was critically dependent on substrate temperature during spray pyrolysis and on post-annealing temperature. Green, photoluminescent films possessed a porous structure while orange films possessed a close packed granular morphology. Green luminescence appears to be due to oxygen vacancies in a layer just below the crystallite surface. (C) 1998 American Institute of Physics. [S0003-6951(98)05216-4].
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页码:2287 / 2294
页数:8
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