The synergistic effect of cobalt on a Pd/Co catalyzed Suzuki-Miyaura cross-coupling in water

被引：27

作者：

You, Li-Xin ^{[1
]}

Liu, Hui-Jie ^{[1
]}

Cui, Lan-Xin ^{[1
]}

Ding, Fu ^{[1
]}

Xiong, Gang ^{[1
]}

Wang, Shu-Ju ^{[1
]}

Ren, Bao-Yi ^{[1
]}

Dragutan, Ileana ^{[2
]}

Dragutan, Valerian ^{[2
]}

Sun, Ya-Guang ^{[1
]}

机构：

[1] Shenyang Univ Chem Technol, Key Lab Inorgan Mol Based Chem Liaoning Prov, Shenyang 110142, Peoples R China

[2] Romanian Acad Bucharest, Inst Organ Chem, Bucharest 060023, Romania

来源：

DALTON TRANSACTIONS | 2016年 / 45卷 / 46期

关键词：

LANTHANIDE COORDINATION POLYMERS; METAL-ORGANIC FRAMEWORKS; HIGHLY EFFICIENT; PALLADIUM; ACID; LIGAND; COMPLEXES; KETONES; SALTS; HECK;

D O I：

10.1039/c6dt03628g

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

This work introduces the new trimetallic complex CoPd2(HBPDC) 2Cl(4)center dot(H2O)(4)(H2BPDC = 2,2'-bipyridine-4,4'-dicarboxylic acid) as a highly efficient and more cost-effective catalyst for a Suzuki-Miyaura reaction proceeding in water, without additives and under aerobic conditions. Catalytic studies revealed a synergistic Co-Pd cooperativity, fostered by ligation through H2BPDC, and accounting for the superior performance of the hetero-bimetallic complex vs. its Co-free counterpart.

引用

页码：18455 / 18458

页数：4

共 50 条

[31] Suzuki-Miyaura Cross-Coupling in Acylation Reactions, Scope and Recent Developments
Blangetti, Marco
Rosso, Helena
Prandi, Cristina
Deagostino, Annamaria
Venturello, Paolo
MOLECULES, 2013, 18 (01) : 1188 - 1213
[32] Nickel-catalyzed Suzuki-Miyaura cross-coupling of C-F bonds
Zhang, Tianhao
Nohira, Itsuki
Chatani, Naoto
ORGANIC CHEMISTRY FRONTIERS, 2021, 8 (14) : 3783 - 3787
[33] Biaryl Ketones by Suzuki-Miyaura Cross-Coupling of Organotrifluoroborates and Acyl Chlorides
Forbes, Alaina M.
Meier, G. Patrick
Jones-Mensah, Ebenezer
Magolan, Jakob
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2016, 2016 (17) : 2983 - 2987
[34] Highly practical boronic acid surrogates for the Suzuki-Miyaura cross-coupling
Bonin, Helene
Leuma-Yona, Rodrigue
Marchiori, Bruno
Demonchaux, Patrice
Gras, Emmanuel
TETRAHEDRON LETTERS, 2011, 52 (10) : 1132 - 1135
[35] Surface catalysed Suzuki-Miyaura cross-coupling by Pd nanoparticles: an operando XAS study
Lee, Adam F.
Ellis, Peter J.
Fairlamb, Ian J. S.
Wilson, Karen
DALTON TRANSACTIONS, 2010, 39 (43) : 10473 - 10482
[36] Stereoselective Preparation and Palladium-Catalyzed Suzuki-Miyaura Cross-Coupling of Alkenyl Sulfoximines
Yasui, Kosuke
Tomishima, Yuichiro
Miura, Tomoya
Yamazaki, Ken
Hirano, Koji
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2025, 64 (11)
[37] Organic Solvent-Free, Pd(II)-Salan Complex-Catalyzed Synthesis of Biaryls via Suzuki-Miyaura Cross-Coupling in Water and Air
Bunda, Szilvia
Udvardy, Antal
Voronova, Krisztina
Joo, Ferenc
JOURNAL OF ORGANIC CHEMISTRY, 2018, 83 (24) : 15486 - 15492
[38] Palladium-Catalyzed Suzuki-Miyaura Cross-Coupling of Secondary α-(Trifluoromethyl)benzyl Tosylates
Brambilla, Marta
Tredwell, Matthew
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2017, 56 (39) : 11981 - 11985
[39] Progress of Nickel-Catalyzed Suzuki-Miyaura Cross-Coupling Reactions of Phenol Derivatives
Chen, Guojun
Du, Jianshi
CHINESE JOURNAL OF ORGANIC CHEMISTRY, 2014, 34 (01) : 65 - 80
[40] Preparing Pd catalysts based on urea ligand via electrospinning for Suzuki-Miyaura cross-coupling reactions
Bao, Guangyang
Fan, Xiaoye
Xu, Tong
Li, Chunping
Bai, Jie
APPLIED ORGANOMETALLIC CHEMISTRY, 2020, 34 (10)

← 1 2 3 4 5 →