The synergistic effect of cobalt on a Pd/Co catalyzed Suzuki-Miyaura cross-coupling in water

被引：27

作者：

You, Li-Xin ^{[1
]}

Liu, Hui-Jie ^{[1
]}

Cui, Lan-Xin ^{[1
]}

Ding, Fu ^{[1
]}

Xiong, Gang ^{[1
]}

Wang, Shu-Ju ^{[1
]}

Ren, Bao-Yi ^{[1
]}

Dragutan, Ileana ^{[2
]}

Dragutan, Valerian ^{[2
]}

Sun, Ya-Guang ^{[1
]}

机构：

[1] Shenyang Univ Chem Technol, Key Lab Inorgan Mol Based Chem Liaoning Prov, Shenyang 110142, Peoples R China

[2] Romanian Acad Bucharest, Inst Organ Chem, Bucharest 060023, Romania

来源：

DALTON TRANSACTIONS | 2016年 / 45卷 / 46期

关键词：

LANTHANIDE COORDINATION POLYMERS; METAL-ORGANIC FRAMEWORKS; HIGHLY EFFICIENT; PALLADIUM; ACID; LIGAND; COMPLEXES; KETONES; SALTS; HECK;

D O I：

10.1039/c6dt03628g

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

This work introduces the new trimetallic complex CoPd2(HBPDC) 2Cl(4)center dot(H2O)(4)(H2BPDC = 2,2'-bipyridine-4,4'-dicarboxylic acid) as a highly efficient and more cost-effective catalyst for a Suzuki-Miyaura reaction proceeding in water, without additives and under aerobic conditions. Catalytic studies revealed a synergistic Co-Pd cooperativity, fostered by ligation through H2BPDC, and accounting for the superior performance of the hetero-bimetallic complex vs. its Co-free counterpart.

引用

页码：18455 / 18458

页数：4

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