The synergistic effect of cobalt on a Pd/Co catalyzed Suzuki-Miyaura cross-coupling in water

被引：27

作者：

You, Li-Xin ^{[1
]}

Liu, Hui-Jie ^{[1
]}

Cui, Lan-Xin ^{[1
]}

Ding, Fu ^{[1
]}

Xiong, Gang ^{[1
]}

Wang, Shu-Ju ^{[1
]}

Ren, Bao-Yi ^{[1
]}

Dragutan, Ileana ^{[2
]}

Dragutan, Valerian ^{[2
]}

Sun, Ya-Guang ^{[1
]}

机构：

[1] Shenyang Univ Chem Technol, Key Lab Inorgan Mol Based Chem Liaoning Prov, Shenyang 110142, Peoples R China

[2] Romanian Acad Bucharest, Inst Organ Chem, Bucharest 060023, Romania

来源：

DALTON TRANSACTIONS | 2016年 / 45卷 / 46期

关键词：

LANTHANIDE COORDINATION POLYMERS; METAL-ORGANIC FRAMEWORKS; HIGHLY EFFICIENT; PALLADIUM; ACID; LIGAND; COMPLEXES; KETONES; SALTS; HECK;

D O I：

10.1039/c6dt03628g

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

This work introduces the new trimetallic complex CoPd2(HBPDC) 2Cl(4)center dot(H2O)(4)(H2BPDC = 2,2'-bipyridine-4,4'-dicarboxylic acid) as a highly efficient and more cost-effective catalyst for a Suzuki-Miyaura reaction proceeding in water, without additives and under aerobic conditions. Catalytic studies revealed a synergistic Co-Pd cooperativity, fostered by ligation through H2BPDC, and accounting for the superior performance of the hetero-bimetallic complex vs. its Co-free counterpart.

引用

页码：18455 / 18458

页数：4

共 38 条

[31] Crystalline Capsules: Metal-Organic Frameworks Locked by Size-Matching Ligand Bolts [J].

Wang, Hao ;

Xu, Jian ;

Zhang, Da-Shuai ;

Chen, Qiang ;

Wen, Rong-Mei ;

Chang, Ze ;

Bu, Xian-He .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2015, 54 (20) :5966-5970

[32] A highly efficient "metalloligand'' strategy for the synthesis of ternary Ln-Ru-W hybrids [J].

Wang, Lei ;

Yang, Weiting ;

Yi, Fei-Yan ;

Wang, Hao ;

Xie, Zhigang ;

Tang, Jinkui ;

Sun, Zhong-Ming .

CHEMICAL COMMUNICATIONS, 2013, 49 (72) :7911-7913

[33] Solvent-regulated assemblies of 1D lanthanide coordination polymers with the tricarboxylate ligand [J].

Wang, Shu-Ju ;

Tian, Yan-Wen ;

You, Li-Xin ;

Ding, Fu ;

Meert, Katrien W. ;

Poelman, Dirk ;

Smet, Philippe F. ;

Ren, Bao-Yi ;

Sun, Ya-Guang .

DALTON TRANSACTIONS, 2014, 43 (09) :3462-3470

[34] Monodispersed Pd-Ni Nanoparticles: Composition Control Synthesis and Catalytic Properties in the Miyaura-Suzuki Reaction [J].

Wu, Yuen ;

Wang, Dingsheng ;

Zhao, Peng ;

Niu, Zhiqiang ;

Peng, Qing ;

Li, Yadong .

INORGANIC CHEMISTRY, 2011, 50 (06) :2046-2048

[35]

Xia J., APPL CATAL B, V200, P39

[36] Synthesis, structure and properties of 2D lanthanide coordination polymers based on N-heterocyclic arylpolycarboxylate ligands [J].

You, Li-Xin ;

Wang, Shu-Ju ;

Xiong, Gang ;

Ding, Fu ;

Meert, Katrien W. ;

Poelman, Dirk ;

Smet, Philippe F. ;

Ren, Bao-Yi ;

Tian, Yan-Wen ;

Sun, Ya-Guang .

DALTON TRANSACTIONS, 2014, 43 (46) :17385-17394

[37] High catalytic activity in aqueous heck and Suzuki-Miyaura reactions catalyzed by novel Pd/Ln coordination polymers based on 2,2'-bipyridine-4,4'-dicarboxylic acid as a heteroleptic ligand [J].

You, Lixin ;

Zhu, Wenli ;

Wang, Shuju ;

Xiong, Gang ;

Ding, Fu ;

Ren, Baoyi ;

Dragutan, Ileana ;

Dragutan, Valerian ;

Sun, Yaguang .

POLYHEDRON, 2016, 115 :47-53

[38] Cooperative effects of lanthanides when associated with palladium in novel, 3D Pd/Ln coordination polymers. Sustainable applications as water-stable, heterogeneous catalysts in carbon-carbon cross-coupling reactions [J].

You, Lixin ;

Zong, Wenhui ;

Xiong, Gang ;

Ding, Fu ;

Wang, Shuju ;

Ren, Baoyi ;

Dragutan, Ileana ;

Dragutan, Valerian ;

Sun, Yaguang .

APPLIED CATALYSIS A-GENERAL, 2016, 511 :1-10

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