A self-assembled, metallo-organic supramolecular frequency doubler

被引：2

作者：

Burke, Luke A. ^{[1
]}

Gonella, Grazia ^{[1
,2
]}

Heirtzler, Fenton ^{[1
]}

Dai, Hai-Lung ^{[2
]}

Jones, Stephanie ^{[3
]}

Zubieta, Jon ^{[3
]}

Roche, Alex J. ^{[1
]}

机构：

[1] Rutgers State Univ, Dept Chem, Camden, NJ 08102 USA

[2] Temple Univ, Dept Chem, Philadelphia, PA 19122 USA

[3] Syracuse Univ, Dept Chem, Ctr Sci & Technol 1 014, Syracuse, NY 13244 USA

来源：

CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 07期

基金：

美国国家科学基金会;

关键词：

NONLINEAR-OPTICAL PROPERTIES; HYPER-RAYLEIGH SCATTERING; COORDINATION NETWORKS; PI-STACKING; CHROMOPHORES; LIGAND; COMPLEXES; DIPOLAR;

D O I：

10.1039/c2cc16199k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The dimeric self-assembly program of a new, multidentate ligand with cuprous ions overcomes crystal packing forces, which leads to C-i symmetry in the solid state, to form a no less than partially C-2-symmetric structure in solution. The resulting tetranitro-substituted dicopper(I) metallocyclophane displays an exceptionally strong second harmonic frequency response (beta = (3000 +/- 600) x 10(-3) esu for a fundamental at 800 nm).

引用

页码：1000 / 1002

页数：3

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