Synthesis, structure and photoluminescence of [N-ethyl-4,4′-bipyridinium][CdBr4] with N-ethyl-4,4′-bipyridinium generated in situ

被引：2
作者：
Chen, Wentong [1 ]
Yao, Zhongliang [2 ]
Huang, Jinshun [3 ]
Liu, Dongsheng [1 ]
Ying, Shaoming [1 ]
Liu, Jiuhui [1 ]
机构：
[1] Jinggangshan Univ, Sch Chem & Chem Engn, Jiangxi Prov Key Lab Coordinat Chem, Jian 343009, Jiangxi, Peoples R China
[2] Fujian Normal Univ, Fuqing Branch, Biol & Chem Engn Dept, Fuqing 350300, Fujian, Peoples R China
[3] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China
来源：
JOURNAL OF CHEMICAL RESEARCH | 2010年 / 11期
关键词：
bipyridine; N-ethyl-4,4 '-bipyridinium cadmium; photoluminescence; HYDROTHERMAL SYNTHESIS; COORDINATION POLYMERS; X-RAY; COMPLEXES; 4,4'-BIPYRIDINE; PHOTOCHROMISM; LIGAND;
D O I：
10.3184/030823410X12875758570086
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A new viologen(4,4'-bipyridinium)-based complex [N-ethyl-4,4'-bipyridinium][CdBr4], in which N-ethyl-4,4'-bipyridinium (EQ(2+)) has been generated in situ, has been synthesised via hydrothermal reaction and structurally characterised by single-crystal X-ray diffraction. [N-ethyl-4,4'-bipyridinium][CdBr4] features an isolated structure, based on an N-ethyl-4,4'-bipyridinium moiety and a cadmium atom terminally bound by four bromine atoms. Photoluminescence investigation reveals a broad and intense emission in blue region, which may originated from pi -> pi* charge-transfer interaction of the N-ethyl-4,4'-bipyridinium moiety.
引用
收藏
页码：616 / 618
页数：3
相关论文
共 26 条
  • [1] [Anonymous], 2002, CRYSTALCLEAR VERS 1
  • [2] Controlled binding of a L-cysteinato cobalt(III) octahedron to a cadmium(II) center
    Aridomi, Takashi
    Kawamoto, Tatsuya
    Konno, Takumi
    [J]. INORGANIC CHEMISTRY, 2007, 46 (04) : 1343 - 1353
  • [3] In situ formation of heterobimetallic salen complexes containing titanium and/or vanadium ions
    Belokon, Yuri N.
    Clegg, William
    Harrington, Ross W.
    North, Michael
    Young, Carl
    [J]. INORGANIC CHEMISTRY, 2008, 47 (09) : 3801 - 3814
  • [4] Metal-assisted in situ formation of a tridentate acetylacetone ligand for complexation of fac-Re(CO)3+ for radiopharmaceutical applications
    Benny, Paul D.
    Fugate, Glenn A.
    Barden, Adam O.
    Morley, Jennifer E.
    Silva-Lopez, Elsa
    Twamley, Brendan
    [J]. INORGANIC CHEMISTRY, 2008, 47 (07) : 2240 - 2242
  • [5] Photochemical and thermal synthesis and characterization of polypyridine ruthenium(II) complexes containing different monodentate ligands
    Bonnet, S
    Collin, JP
    Gruber, N
    Sauvage, JP
    Schofield, ER
    [J]. DALTON TRANSACTIONS, 2003, (24) : 4654 - 4662
  • [6] High-frequency, high-field EPR;: Magnetic susceptibility;: and x-ray studies on a ferromagnetic heterometallic complex of diethanolamine (H2L), [Cu4(NH3)4(HL)4][CdBr4]Br2•3dmf•H2O
    Buvaylo, EA
    Kokozay, VN
    Vassilyeva, OY
    Skelton, BW
    Jezierska, J
    Brunel, LC
    Ozarowski, A
    [J]. INORGANIC CHEMISTRY, 2005, 44 (02) : 206 - 216
  • [7] EFFECTS OF CONFORMATIONAL CHANGE IN THE ACCEPTOR ON INTRAMOLECULAR ELECTRON-TRANSFER
    CHEN, PY
    CURRY, M
    MEYER, TJ
    [J]. INORGANIC CHEMISTRY, 1989, 28 (12) : 2271 - 2280
  • [8] Synthesis, structure and properties of (4,4′-H2bipy)[HgBr4]-H20 with strong fluorescence
    Chen, Wen-Tong
    Zeng, Xi-Rui
    Fang, Xiao-Niu
    Li, Xin-Fa
    Liu, Li-Min
    [J]. INORGANIC CHEMISTRY COMMUNICATIONS, 2007, 10 (02) : 223 - 225
  • [9] 3-(Hydroxydiphenylmethyl)-2-(methoxymethoxy)benzaldehyde
    Chen, WZ
    Zeng, QL
    Fang, H
    Gao, YX
    Zhao, YF
    [J]. ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2006, 62 : O869 - O870
  • [10] Solvothermal in situ metal/ligand reactions: A new bridge between coordination chemistry and organic synthetic chemistry
    Chen, Xiao-Ming
    Tong, Ming-Liang
    [J]. ACCOUNTS OF CHEMICAL RESEARCH, 2007, 40 (02) : 162 - 170
123