Electrodeposition of lithium film under dynamic conditions and its application in all-solid-state rechargeable lithium battery

被引：22

作者：

Yang, XL ^{[1
]}

Wen, ZY ^{[1
]}

Zhu, XJ ^{[1
]}

Huang, SH ^{[1
]}

机构：

[1] Chinese Acad Sci, Shanghai Inst Ceram, Grad Sch, Shanghai 200050, Peoples R China

来源：

SOLID STATE IONICS | 2005年 / 176卷 / 11-12期

基金：

中国国家自然科学基金;

关键词：

electrodeposition; dynamic; all-solid-state; lithium; SEI;

D O I：

10.1016/j.ssi.2005.02.009

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The morphology of lithium electrodeposited under dynamic conditions from LiPF6/(EC+DMC) solution was observed. The dendritic lithium was effectively suppressed at the current density as high as 2.0 mA cm(-2) under dynamic conditions compared to the electrodeposition at 0.5 mA cm(-2) under static conditions. Impedance measurements were employed to monitor the formation and breaking of surface layers during electrodeposition. The experimental results showed that the interface stability of Li/P(EO)(20)Li(CF3SO2)(2)N-10 wt.% gamma-LiAlO2 using electrodeposited lithium film was much better than that using commercial lithium foil, which demonstrated that the electrodeposited lithium was a preferable candidate as anode for all-solid-state lithium battery. (c) 2005 Elsevier B.V. All rights reserved.

引用

页码：1051 / 1055

页数：5

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