Electrodes Functionalized with the 2,2,6,6-Tetramethylpiperidinyloxy Radical for the Waste-Free Oxidation of Alcohols

被引：40

作者：

Ciriminna, Rosaria ^{[1
]}

Palmisano, Giovanni ^{[2
]}

Pagliaro, Mario ^{[1
]}

机构：

[1] CNR, Ist Studio Mat Nanostrutturati, I-90146 Palermo, Italy

[2] Masdar Inst Sci & Technol, Inst Ctr Water & Environm iWater, Dept Chem & Environm Engn, Abu Dhabi, U Arab Emirates

来源：

CHEMCATCHEM | 2015年 / 7卷 / 04期

关键词：

alcohols; electrochemistry; organocatalysis; oxidation; waste prevention; MEDIATED ELECTROOXIDATION; ORGANIC ELECTROSYNTHESIS; TEMPO;

D O I：

10.1002/cctc.201402896

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Electrodes functionalised with the organocatalyst 2,2,6,6-tetramethylpiperidinyloxy (TEMPO) moiety hold great potential for the development of waste-free industrial synthesis of valuable carbonyl compounds using electrons and alcohols as the only reactants. Since the inception of the first active electrode in 1988, a number of different electrodes have been developed to the recent fastest TEMPO-mediated alcohol oxidation process ever reported. In addition to good activity and broad applicability to different substrates, the electrode stability is the crucial factor that will guide the adoption of this eminently clean technology by the fine chemical and pharmaceutical industry.

引用

页码：552 / 558

页数：7

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