Phase transitions of Na-ion layered oxide materials and their influence on properties

被引：18

作者：

Fei-Xiang, Ding ^{[1
,3
]}

Xiao-Hui, Rong ^{[1
,3
]}

Hai-Bo, Wang ^{[1
]}

Yang, Yang ^{[1
,2
]}

Zi-Lin, Hu ^{[1
,2
]}

Rong-Bin, Dang ^{[1
]}

Ya-Xiang, Lu ^{[1
,3
]}

Yong-Sheng, Hu ^{[1
,2
,3
]}

机构：

[1] Chinese Acad Sci, Inst Phys, Beijing 100190, Peoples R China

[2] Univ Chinese Acad Sci, Coll Mat Sci & Optoelect Technol, Beijing 100049, Peoples R China

[3] Chinese Acad Sci, Inst Phys, Huairou Div, Beijing 101400, Peoples R China

来源：

ACTA PHYSICA SINICA | 2022年 / 71卷 / 10期

基金：

中国博士后科学基金; 中国国家自然科学基金;

关键词：

Na-ion battery; layered oxide; cathode material; phase transformation mechanism; X LESS-THAN; CATHODE MATERIALS; ELECTRODE MATERIALS; HIGH-VOLTAGE; LONG-LIFE; SODIUM; BATTERIES; P2-TYPE; CAPACITY; DEINTERCALATION;

D O I：

10.7498/aps.71.20220291

中图分类号：

O4 [物理学];

学科分类号：

0702 ;

摘要：

Na-ion batteries possess great potential applications in the large-scale energy storage. The Na-ion layered oxide cathode (NaxTMO2) has received increasing attention in scientific and industrial research due to its high capacity, easy manufacture, adjustable voltage, and low cost. However, the larger the Na+ radius and the stronger the Na+-Na+ electrostatic repulsion is, which will lead to various structural configurations and complex structural transitions, resulting in multiple structure-property connections. In this paper, the structural types of Na-ion layered transition metal oxide cathode materials are introduced, and their structural evolutions during Na+ de/intercalation are summarized for revealing the mechanism for structural transformation of Na-ion layered transition-metal oxide cathode material and its effect on electrochemical performance; the existing challenges are discussed; the improvement strategies are proposed finally.

引用

页数：25

共 77 条

[1] Anionic Redox Activity in a Newly Zn-Doped Sodium Layered Oxide P2-Na2/3Mn1-yZnyO2 (0 < y < 0.23) [J].

Bai, Xue ;

Sathiya, Mariyappan ;

Mendoza-Sanchez, Beatriz ;

Iadecola, Antonella ;

Vergnet, Jean ;

Dedryvere, Remi ;

Saubanere, Matthieu ;

Abakumov, Artem M. ;

Rozier, Patrick ;

Tarascon, Jean-Marie .

ADVANCED ENERGY MATERIALS, 2018, 8 (32)

[2] The Scale-up and Commercialization of Nonaqueous Na-Ion Battery Technologies [J].

Bauer, Alexander ;

Song, Jie ;

Vail, Sean ;

Pan, Wei ;

Barker, Jerry ;

Lu, Yuhao .

ADVANCED ENERGY MATERIALS, 2018, 8 (17)

[3] STUDY OF THE NAXCRO2 AND NAXNIO2 SYSTEMS BY ELECTROCHEMICAL DESINTERCALATION [J].

BRACONNIER, JJ ;

DELMAS, C ;

HAGENMULLER, P .

MATERIALS RESEARCH BULLETIN, 1982, 17 (08) :993-1000

[4] ELECTROCHEMICAL BEHAVIOR OF THE PHASES NAXCOO2 [J].

BRACONNIER, JJ ;

DELMAS, C ;

FOUASSIER, C ;

HAGENMULLER, P .

MATERIALS RESEARCH BULLETIN, 1980, 15 (12) :1797-1804

[5] Porous NiCo2O4Nanowire Arrays as Supercapacitor Electrode Materials with Extremely High Cycling Stability [J].

Chen, Chaoxian ;

Zhao, Chenyang ;

Li, Cuihua ;

Liu, Jianhong ;

Gui, Dayong .

CHEMICAL RESEARCH IN CHINESE UNIVERSITIES, 2020, 36 (04) :715-720

[6] Structural characterisation of the highly deintercalated LixNi1.02O2 phases (with x ≤ 0.30) [J].

Croguennec, L ;

Pouillerie, C ;

Mansour, AN ;

Delmas, C .

JOURNAL OF MATERIALS CHEMISTRY, 2001, 11 (01) :131-141

[7] O3-NaxMn1/3Fe2/3O2 as a positive electrode material for Na-ion batteries: structural evolutions and redox mechanisms upon Na+ (de) intercalation [J].

de Boisse, B. Mortemard ;

Cheng, J. -H. ;

Carlier, D. ;

Guignard, M. ;

Pan, C. -J. ;

Bordere, S. ;

Filimonov, D. ;

Drathen, C. ;

Suard, E. ;

Hwang, B. -J. ;

Wattiaux, A. ;

Delmas, C. .

JOURNAL OF MATERIALS CHEMISTRY A, 2015, 3 (20) :10976-10989

[8] Coulombic self-ordering upon charging a large-capacity layered cathode material for rechargeable batteries [J].

de Boisse, Benoit Mortemard ;

Reynaud, Marine ;

Ma, Jiangtao ;

Kikkawa, Jun ;

Nishimura, Shin-ichi ;

Casas-Cabanas, Montse ;

Delmas, Claude ;

Okubo, Masashi ;

Yamada, Atsuo .

NATURE COMMUNICATIONS, 2019, 10 (1)

[9] Intermediate honeycomb ordering to trigger oxygen redox chemistry in layered battery electrode [J].

de Boisse, Benoit Mortemard ;

Liu, Guandong ;

Ma, Jiangtao ;

Nishimura, Shin-ichi ;

Chung, Sai-Cheong ;

Kiuchi, Hisao ;

Harada, Yoshihisa ;

Kikkawa, Jun ;

Kobayashi, Yoshio ;

Okubo, Masashi ;

Yamada, Atsuo .

NATURE COMMUNICATIONS, 2016, 7

[10] STRUCTURAL CLASSIFICATION AND PROPERTIES OF THE LAYERED OXIDES [J].

DELMAS, C ;

FOUASSIER, C ;

HAGENMULLER, P .

PHYSICA B & C, 1980, 99 (1-4) :81-85

← 1 2 3 4 5 6 7 8 →