A 1D → 3D Two-Fold Interpenetration Array Formed by Hydrogen-Bonding Interactions

被引:6
作者
Ma, De-Yun [1 ]
Guo, Hai-Fu [1 ]
Lu, Kuan [1 ]
Pan, Yong [1 ,2 ]
Qin, Liang [1 ]
Blatov, Vladislav A. [3 ]
机构
[1] Zhaoqing Univ, Coll Chem & Chem Engn, Zhaoqing 526061, Peoples R China
[2] Inner Mongolia Univ Technol, Coll Chem Engn, Hohhot 010051, Peoples R China
[3] Samara State Univ, Samara 443011, Russia
来源
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2012年 / 638卷 / 06期
关键词
Hydrothermal synthesis; Crystal structure; Interpenetration; Hydrogen bonds; Cobalt; COPPER(II) COMPLEXES; COORDINATION POLYMERS; CRYSTAL-STRUCTURES; 4,4'-BIPYRIDINE; NETWORKS; TOPOLOGY; NET;
D O I
10.1002/zaac.201100545
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The self-assembly of 4'-hydroxy-biphenyl-4-carboxylic acid (H2hbc), 4, 4'-bipyridine (4, 4'-bpy) with a cobalt salt under hydrothermal conditions yielded a novel dinuclear cobalt(II) coordination polymer, {[Co(Hhbc)2(4, 4'-bpy)]center dot H2O}n (1), where the coordinating polymeric chains are connected together through hydrogen bonding into a 3D framework of the primitive cubic (pcu) topology. Two pcu frameworks are interweaved into a 3D twofold Class Ia interpenetrating array.
引用
收藏
页码:992 / 995
页数:4
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