Synthesis and Crystal Structure of a N,N,N′-tri(2-hydroxy-5-methylbenzyl)-1,2-ethanediamine

被引：0
|
作者：
Wang Nuan-Sheng [1 ]
Wang Yong-Tao [1 ]
Li Jun-Ying [1 ]
Li Tian-Duo [1 ]
机构：
[1] Shandong Polytech Univ, Shandong Prov Key Lab Fine Chem, Jinan 250353, Peoples R China
来源：
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2011年 / 30卷 / 11期
关键词：
Mannich reaction; aminophenol ligand; crystal structure;
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
An aminophenol ligand, N,N,N'-tri(2-hydroxy-5-methylbenzyl)-1,2-ethanediamine, was prepared through the Mannich reaction, and structurally characterized by NMR, IR, MS and single-crystal X-ray diffraction. The title compound (C(26)H(32)N(2)O(3), M(r) = 420.54) belongs to the monoclinic system, space group P2(1)/n with a = 8.6233(14), b = 10.2655(16), c = 26.017(4) angstrom, beta = 95.797(2)degrees, V = 2291.3(6) angstrom(3), Z = 4, the final R = 0.0461 and wR = 0.1139 for 4267 unique reflections (R(int) = 0.028) with 11691 observed ones (I > 2 sigma(I)).
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页码：1533 / 1536
页数：4
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