Influence of the non-metal species on the oxidation kinetics of Hf, HfN, HfC, and HfB2 coatings

被引：37
作者：
Glechner, T. [1 ]
Hudak, O. E. [1 ]
Wojcik, T. [1 ]
Haager, L. [2 ]
Bohrn, F. [2 ]
Hutter, H. [2 ]
Hunold, O. [3 ]
Ramm, J. [3 ]
Kolozsvari, S. [4 ]
Pitthan, E. [5 ]
Primetzhofer, D. [5 ]
Riedl, H. [1 ,6 ]
机构：
[1] TU Wien, Christian Doppler Lab Surface Engn High Performan, Vienna, Austria
[2] TU Wien, Inst Chem Technol & Analyt, A-1060 Vienna, Austria
[3] Oerlikon Surface Solut AG, Oerlikon Balzers, FL-9496 Balzers, Liechtenstein
[4] Plansee Composite Mat GmbH, D-86983 Lechbruck, Germany
[5] Uppsala Univ, Dept Phys & Astron, SE-75120 Uppsala, Sweden
[6] TU Wien, Inst Mat Sci & Technol, A-1060 Vienna, Austria
来源：
MATERIALS & DESIGN | 2021年 / 211卷
关键词：
Thin films; Borides; Oxide-film growth kinetics; Oxidation; Hafnium; TITANIUM ALUMINUM NITRIDE; TEMPERATURE; RESISTANCE; CARBIDES; BEHAVIOR; FILMS;
D O I：
10.1016/j.matdes.2021.110136
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
The influence of the non-metal species on the oxidation resistance of transition metal ceramic based thin films is still unclear. For this purpose, we thoroughly investigated the oxide scale formation of a metal (Hf), carbide (HFC0.96), nitride (HfB1.5), and boride (HfB2.3) coating grown by physical vapor deposition. The non-metal species decisively affect the onset temperature of oxidation, ranging between 550 degrees C for HfC0.96 to 840 degrees C for HfN1.5. HfB2.3 and HfN1.5 obtain the slowest oxide scale kinetic following a parabolic law with k(p) values of 4.97.10(-10) and 5.66.10(-11) kg(2) m(-4) s(-1) at 840 degrees C, respectively. A characteristic feature for the oxide scale on Hf coatings, is a columnar morphology and a substantial oxygen inward diffusion. HfC0.96 reveals an ineffective oxycarbide based scale, whereas HfN(1.5 )features a scale with globular HfO2 grains. HfB(2.3 )exhibits a layered scale with a porous boron rich region on top, followed by a highly dense and crystalline HfO2 beneath. Furthermore, HfB(2.3 )presents a hardness of 47.7 +/- 2.7 GPa next to an exceptional low inward diffusion of oxygen during oxidation. This study showcases the strong influence of the non-metallic bonding partner despite the same metallic basis, as well as the huge potential for HfB2 based coatings also for oxidative environments. (C) 2021 Published by Elsevier Ltd.
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页数：12
相关论文
共 41 条
[1]   Ultra-high oxidation resistance of nano-structured thin films [J].
Aschauer, E. ;
Wojcik, T. ;
Polcik, P. ;
Hunold, O. ;
Arndt, M. ;
Dalbauer, V ;
Mayrhofer, P. H. ;
Felfer, P. ;
Riedl, H. .
MATERIALS & DESIGN, 2021, 201
[2]   The formation of a homogeneous α-alumina coating on a Ni-based superalloy from a layer stack deposited by cathodic arc evaporation [J].
Ast, J. ;
Balogh-Michels, Z. ;
Dobeli, M. ;
Dommann, A. ;
Gindrat, M. ;
Maeder, X. ;
Neels, A. ;
Polyakov, M. N. ;
Rudigier, H. ;
Widrig, B. ;
Ramm, J. .
SURFACE & COATINGS TECHNOLOGY, 2019, 360 :329-334
[3]   Unprecedented thermal stability of inherently metastable titanium aluminum nitride by point defect engineering [J].
Baben, Moritz to ;
Hans, Marcus ;
Primetzhofer, Daniel ;
Evertz, Simon ;
Ruess, Holger ;
Schneider, Jochen M. .
MATERIALS RESEARCH LETTERS, 2017, 5 (03) :158-169
[4]   Multifunctional ZrB2-rich Zr1-xCrxBy thin films with enhanced mechanical, oxidation, and corrosion properties [J].
Bakhit, Babak ;
Dorri, Samira ;
Kooijman, Agnieszka ;
Wu, Zhengtao ;
Lu, Jun ;
Rosen, Johanna ;
Mol, Johannes M. C. ;
Hultman, Lars ;
Petrov, Ivan ;
Greene, J. E. ;
Greczynski, Grzegorz .
VACUUM, 2021, 185
[5]   Improving the high-temperature oxidation resistance of TiB2 thin films by alloying with Al [J].
Bakhit, Babak ;
Palisaitis, Justinas ;
Thornberg, Jimmy ;
Rosen, Johanna ;
Persson, Per O. A. ;
Hultman, Lars ;
Petrov, Ivan ;
Greene, J. E. ;
Greczynski, Grzegorz .
ACTA MATERIALIA, 2020, 196 :677-689
[6]   Valence electron concentration as an indicator for mechanical properties in rocksalt structure nitrides, carbides and carbonitrides [J].
Balasubramanian, Karthik ;
Khare, Sanjay V. ;
Gall, Daniel .
ACTA MATERIALIA, 2018, 152 :175-185
[7]  
Birks N, 2006, INTRODUCTION TO THE HIGH-TEMPERATURE OXIDATION OF METALS, 2ND EDITION, P1, DOI 10.1017/CBO9781139163903
[8]  
Burgel R., 2011, Handbuch Hochtemperaturwerkstofftechnik - Grundlagen, Werkstoffbeanspruchungen, Hochtemperaturlegierungen und -beschichtungen, V4
[9]   Effect of high temperature oxidation on the radiative properties of HfC-based ceramics [J].
Charpentier, Ludovic ;
Balat-Pichelin, Marianne ;
Sans, Jean-Louis ;
Sciti, Diletta ;
Silvestroni, Laura .
CORROSION SCIENCE, 2017, 126 :255-264
[10]   Thermal stability and oxidation resistance of Ti-Al-N coatings [J].
Chen, Li ;
Paulitsch, Joerg ;
Du, Yong ;
Mayrhofer, Paul H. .
SURFACE & COATINGS TECHNOLOGY, 2012, 206 (11-12) :2954-2960
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