Photochemically Driven Reverse Water-Gas Shift at Ambient Conditions mediated by a Nickel Pincer Complex

被引：27

作者：

Schneck, Felix ^{[1
]}

Schendzielorz, Florian ^{[1
]}

Hatami, Nareh ^{[1
]}

Finger, Markus ^{[1
]}

Wuertele, Christian ^{[1
]}

Schneider, Sven ^{[1
]}

机构：

[1] Georg August Univ, Inst Anorgan Chem, Tammannstr 4, D-37077 Gottingen, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2018年 / 57卷 / 44期

基金：

欧洲研究理事会;

关键词：

CO2; hydrogenation; nickel; photochemistry; pincer ligands; CARBON-DIOXIDE; HOMOGENEOUS CATALYSIS; CO2; REDUCTION; MOLECULAR ELECTROCATALYSTS; ELECTROCHEMICAL REDUCTION; HYDROGENATION; H-2; PORPHYRINS; ACTIVATION; REACTIVITY;

D O I：

10.1002/anie.201803396

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The endothermic reverse water-gas shift reaction (rWGS) for direct CO2 hydrogenation to CO is an attractive approach to carbon utilization. However, direct CO2 hydrogenation with molecular catalysts generally gives formic acid instead of CO as a result of the selectivity of CO2 insertion into M-H bonds. Based on the photochemical inversion of this selectivity, several synthetic pathways are presented for CO selective CO2 reduction with a nickel pincer platform including the first example of a photodriven rWGS cycle at ambient conditions.

引用

页码：14482 / 14487

页数：6

共 42 条

[1] Towards a methanol economy based on homogeneous catalysis: methanol to H2 and CO2 to methanol [J].

Alberico, E. ;

Nielsen, M. .

CHEMICAL COMMUNICATIONS, 2015, 51 (31) :6714-6725

[2] Bottom-Up Construction of a CO2-Based Cycle for the Photocarbonylation of Benzene, Promoted by a Rhodium(I) Pincer Complex [J].

Anaby, Aviel ;

Feller, Moran ;

Ben-David, Yehoshoa ;

Leitus, Gregory ;

Diskin-Posner, Yael ;

Shimon, Linda J. W. ;

Milstein, David .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2016, 138 (31) :9941-9950

[3] Frontiers, Opportunities, and Challenges in Biochemical and Chemical Catalysis of CO2 Fixation [J].

Appel, Aaron M. ;

Bercaw, John E. ;

Bocarsly, Andrew B. ;

Dobbek, Holger ;

DuBois, Daniel L. ;

Dupuis, Michel ;

Ferry, James G. ;

Fujita, Etsuko ;

Hille, Russ ;

Kenis, Paul J. A. ;

Kerfeld, Cheal A. ;

Morris, Robert H. ;

Peden, Charles H. F. ;

Portis, Archie R. ;

Ragsdale, Stephen W. ;

Rauchfuss, Thomas B. ;

Reek, Joost N. H. ;

Seefeldt, Lance C. ;

Thauer, Rudolf K. ;

Waldrop, Grover L. .

CHEMICAL REVIEWS, 2013, 113 (08) :6621-6658

[4] Molecular artificial photosynthesis [J].

Berardi, Serena ;

Drouet, Samuel ;

Francas, Laia ;

Gimbert-Surinach, Carolina ;

Guttentag, Miguel ;

Richmond, Craig ;

Stoll, Thibaut ;

Llobet, Antoni .

CHEMICAL SOCIETY REVIEWS, 2014, 43 (22) :7501-7519

[5]

Bourrez M., 2014, ANGEW CHEM, V126, P244

[6] Pulsed-EPR Evidence of a Manganese(II) Hydroxycarbonyl Intermediate in the Electrocatalytic Reduction of Carbon Dioxide by a Manganese Bipyridyl Derivative [J].

Bourrez, Marc ;

Orio, Maylis ;

Molton, Florian ;

Vezin, Herve ;

Duboc, Carole ;

Deronzier, Alain ;

Chardon-Noblat, Sylvie .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2014, 53 (01) :240-243

[7] Molecular Electrocatalysts for Oxidation of Hydrogen Using Earth-Abundant Metals: Shoving Protons Around with Proton Relays [J].

Bullock, R. Morris ;

Helm, Monte L. .

ACCOUNTS OF CHEMICAL RESEARCH, 2015, 48 (07) :2017-2026

[8] A Bimetallic Nickel-Gallium Complex Catalyzes CO2 Hydrogenation via the Intermediacy of an Anionic d10 Nickel Hydride [J].

Cammarota, Ryan C. ;

Vollmer, Matthew V. ;

Xie, Jing ;

Ye, Jingyun ;

Linehan, John C. ;

Burgess, Samantha K. ;

Appel, Aaron M. ;

Gagliardi, Laura ;

Lu, Connie C. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2017, 139 (40) :14244-14250

[9] Nickel and Iron Pincer Complexes as Catalysts for the Reduction of Carbonyl Compounds [J].

Chakraborty, Sumit ;

Bhattacharya, Papri ;

Dai, Huiguang ;

Guan, Hairong .

ACCOUNTS OF CHEMICAL RESEARCH, 2015, 48 (07) :1995-2003

[10] Current Issues in Molecular Catalysis Illustrated by Iron Porphyrins as Catalysts of the CO2-to-CO Electrochemical Conversion [J].

Costentin, Cyrille ;

Robert, Marc ;

Saveant, Jean-Michel .

ACCOUNTS OF CHEMICAL RESEARCH, 2015, 48 (12) :2996-3006

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