Pressure drop behavior in the anode flow field of liquid feed direct methanol fuel cells

被引:58
作者
Yang, H [1 ]
Zhao, TS [1 ]
Ye, Q [1 ]
机构
[1] Hong Kong Univ Sci & Technol, Dept Mech Engn, Kowloon, Hong Kong, Peoples R China
关键词
direct methanol fuel cells; serpentine channel; two-phase flow; pressure drop;
D O I
10.1016/j.jpowsour.2004.09.036
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In this work, we experimentally investigated the two-phase flow pressure drop behavior in the anode flow field of an in-house fabricated direct methanol fuel cell (DMFC). The anode flow field consisted of a single serpentine flow channel with a cross-sectional area of 2.0 x 2.0 mm(2) and a total length of 420 mm. The pressure drops between the inlet and the outlet of the flow channel were measured by varying current density. The experimental results show that at low current densities, the pressure drop increased with increasing current density. After reaching a peak at certain current density, however, the pressure drop began to decrease with increasing current density. It has also been shown that the pressure drop always increased with the methanol solution flow rate. However, either lower or higher flow rates deteriorated the cell performance. The experimental results further show that the pressure drop became almost independent of the Current density when the methanol solution flow rate became sufficiently high. The study also reveals that both temperature and methanol concentration had significant influence on the cell performance. but their effects on the pressure drop were small. (c) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码:117 / 124
页数:8
相关论文
共 31 条
[1]   Pressure drop modelling for liquid feed direct methanol fuel cells Part 1. Model development [J].
Argyropoulos, P ;
Scott, K ;
Taama, WM .
CHEMICAL ENGINEERING JOURNAL, 1999, 73 (03) :217-227
[2]   Pressure drop modelling for liquid feed direct methanol fuel cells Part II. Model based parametric analysis [J].
Argyropoulos, P ;
Scott, K ;
Taama, WM .
CHEMICAL ENGINEERING JOURNAL, 1999, 73 (03) :229-245
[3]  
Carey VP, 1992, LIQUID VAPOR PHASE C, P411
[4]  
Collier J.G., 1994, CONVECTIVE BOILING C, V3rd ed., P34
[5]   Fuel cells: a survey of current developments [J].
Cropper, MAJ ;
Geiger, S ;
Jollie, DM .
JOURNAL OF POWER SOURCES, 2004, 131 (1-2) :57-61
[6]   Stainless steel as a bipolar plate material for solid polymer fuel cells [J].
Davies, DP ;
Adcock, PL ;
Turpin, M ;
Rowen, SJ .
JOURNAL OF POWER SOURCES, 2000, 86 (1-2) :237-242
[7]   Bipolar plate materials for solid polymer fuel cells [J].
Davies, DP ;
Adcock, PL ;
Turpin, M ;
Rowen, SJ .
JOURNAL OF APPLIED ELECTROCHEMISTRY, 2000, 30 (01) :101-105
[8]   International activities in DMFC R&D:: status of technologies and potential applications [J].
Dillon, R ;
Srinivasan, S ;
Aricò, AS ;
Antonucci, V .
JOURNAL OF POWER SOURCES, 2004, 127 (1-2) :112-126
[9]   Fuel cells for portable applications [J].
Dyer, CK .
JOURNAL OF POWER SOURCES, 2002, 106 (1-2) :31-34
[10]   METHANOL ELECTROOXIDATION ON WELL-CHARACTERIZED PT-RN ALLOYS [J].
GASTEIGER, HA ;
MARKOVIC, N ;
ROSS, PN ;
CAIRNS, EJ .
JOURNAL OF PHYSICAL CHEMISTRY, 1993, 97 (46) :12020-12029