Solid phase colorimetric determination of iodine in food grade salt using polymethacrylate matrix

被引:25
作者
Gavrilenko, Nataliya A. [1 ]
Fedan, Dmitrii A. [2 ]
Saranchina, Nadezhda V. [2 ]
Gavrilenko, Mikhail A. [1 ]
机构
[1] Tomsk Polytech Univ, Dept Chem Engn, Tomsk 634050, Russia
[2] Tomsk State Univ, Dept Analyt Chem, Tomsk 634050, Russia
基金
俄罗斯科学基金会;
关键词
Iodine; Iodide; Food grade salt; Colorimetric sensor; Solid phase spectrophotometry; EXTRACTION; SAMPLES; PRECONCENTRATION; TRENDS; GREEN;
D O I
10.1016/j.foodchem.2018.12.037
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
A novel colorimetric sensor has been proposed for sensitive and accurate detection of iodine forms using polymethacrylate matrix, which also has the outlook for use with samples without pre-treatment and is suitable to fit in a portable instrument for in situ iodine analysis. This determination method is based on interaction of polymethacrylate matrix with iodine forms followed by measurement of absorbance at 370 nm. The principle of this colorimetric sensor is not ordinary colorimetry, but a new colorimetric strategy that combines solid phase extraction and spectrophotometric determination of a target substance following completion of the color change processes. This method ensures determination of 0.05-80.0 mu g.g(-1) of iodine with the detection limit of 0.02 mu g.g(-1). The testing results show that this polymethacrylate matrix can be used for determination of iodine in solutions, food grade salt and iodinated mineral water.
引用
收藏
页码:15 / 19
页数:5
相关论文
共 35 条
[1]   Global Iodine Status in 2011 and Trends over the Past Decade [J].
Andersson, Maria ;
Karumbunathan, Vallikkannu ;
Zimmermann, Michael B. .
JOURNAL OF NUTRITION, 2012, 142 (04) :744-750
[2]  
[Anonymous], 2007, ASSESSMENT IODINE DE, VThird
[3]   Rapid, specific determination of iodine and iodide by combined solid-phase extraction/diffuse reflectance spectroscopy [J].
Arena, MP ;
Porter, MD ;
Fritz, JS .
ANALYTICAL CHEMISTRY, 2002, 74 (01) :185-190
[4]   Simultaneous determination of perfluoroalkyl iodides, perfluoroalkane sulfonamides, fluorotelomer alcohols, fluorotelomer iodides and fluorotelomer acrylates and methacrylates in water and sediments using solid-phase microextraction-gas chromatography/mass spectrometry [J].
Bach, Cristina ;
Boiteux, Virginie ;
Hemard, Jessica ;
Colin, Adeline ;
Rosin, Christophe ;
Munoz, Jean-Francois ;
Dauchy, Xavier .
JOURNAL OF CHROMATOGRAPHY A, 2016, 1448 :98-106
[5]   Molecular iodine preconcentration and determination in aqueous samples using poly(vinylpyrrolidone) containing membranes [J].
Bhagat, P. R. ;
Pandey, A. K. ;
Acharya, R. ;
Nair, A. G. C. ;
Rajurkar, N. S. ;
Reddy, A. V. R. .
TALANTA, 2008, 74 (05) :1313-1320
[6]   Solid phase extraction of trace elements [J].
Camel, V .
SPECTROCHIMICA ACTA PART B-ATOMIC SPECTROSCOPY, 2003, 58 (07) :1177-1233
[7]   Determination of major sodium iodide symporter (NIS) inhibitors in drinking waters using ion chromatography with conductivity detector [J].
Cengiz, Mehmet Fatih ;
Bilgin, Ayse Keyser .
JOURNAL OF PHARMACEUTICAL AND BIOMEDICAL ANALYSIS, 2016, 120 :190-197
[8]  
Dearth-Wesley Tracy, 2004, Food and Nutrition Bulletin, V25, P130
[9]  
Della Fonte A. R., 2016, J APPL PHARM SCI, V6, P22
[10]   Principles and applications of colorimetric solid-phase extraction with negligible depletion [J].
Dias, NC ;
Porter, MD ;
Fritz, JS .
ANALYTICA CHIMICA ACTA, 2006, 558 (1-2) :230-236