Copper(I) Complexes of N-thiophosphorylated Bis-thiourea [CH2NHC(S)NHP(S)(OiPr)2]2 and Phosphines (PPh3, Ph2P(CH2)1-3PPh2, Ph2P(C5H4FeC5H4)PPh2): Versatile Structures and Luminescence

被引：0
作者：
Safin, Damir A. [1 ]
Babashkina, Maria G. [1 ]
Klein, Axel [1 ]
机构：
[1] Univ Cologne, Inst Anorgan Chem, D-50939 Cologne, Germany
来源：
CROATICA CHEMICA ACTA | 2010年 / 83卷 / 03期
关键词：
coordination chemistry; copper(I); thiophosphorylthiourea; phosphine; luminescence; CRYSTAL-STRUCTURES; HL; 2,5-DITHIOBIUREA;
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Reaction of the potassium solution of [CH2NHC(S)NHP(S)(OiPr)(2)](2) (H2L) with [Cu(PPh3)(3)I] or a mixture of Cul and Ph2P(CH2)(1-3)PPh2 or Ph2P(C5H4FeC5H4)PPh2 in aqueous EtOH/CH2Cl2 leads to binuclear [Cu-2(PPh3)(2)L] (1), [Cu-2(Ph2PCH2PPh2)L] (2), [Cu-2{Ph2P(CH2)(2)PPh2}(2)L] (3), [Cu-2{Ph2P(CH2)(3)PPh2}(2)L] (4) or [Cu-2{Ph2P(C5H4FeC5H4)PPh2}(2)L] (5) complexes. The structures of these compounds were investigated by IR, H-1 and P-31{H-1} NMR spectroscopy; their compositions were examined by microanalysis. The luminescent properties of complexes 1-5 in the solid state are reported.
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页码：353 / 356
页数：4
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