Sorption of nitrophenols derivatives from aqueous solutions by alginate beads

被引:0
作者
Peretz, Sandu [1 ]
Cinteza, Otilia [2 ]
Peretz, Angela [3 ]
机构
[1] Inst Chim Fiz I Murgulescu, Lab Chim Coloizilor, Bucharest 060021, Romania
[2] Univ Bucuresti, Catedra Chim Fiz, Bucharest 030018, Romania
[3] Agentia Natl Pentru Substante Preparate Chim Peri, Bucharest, Romania
来源
REVISTA DE CHIMIE | 2007年 / 58卷 / 11期
关键词
sorption; nitrophenol; alginate; bead;
D O I
暂无
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The sorption of some pollutants from aqueous solutions can performing efficiently using biopolymers such as alginates. Alginate is a natural linear polysaccharide extracted from marine brown algae, a copolymer of beta-D-mannuronic and alpha-L-guluronic acid residues. The aim of this study was to examine the sorption capacity of alginate beads to remove 2-nitrophenol and 2-nitrophenol potassium salt from water solutions. The sorption and kinetic experiments of nitrophenols uptake by alginate beads were carried out under different values of pH, initial concentration of pollutants and the number of alginate gel beads. The removal efficiency of nitrophenols derivatives increases with the pH values and the quantity of alginate beads and decreases with the increasing of initial pollutant concentration. The sorption of pollutants occurs rapidly in the first 12 h, followed by a slow process that takes about 72 h.
引用
收藏
页码:1129 / 1133
页数:5
相关论文
共 24 条
[1]   PHOTOCHEMISTRY AND ENVIRONMENT .13. PHOTOTRANSFORMATION OF 2-NITROPHENOL IN AQUEOUS-SOLUTION [J].
ALIF, A ;
PILICHOWSKI, JF ;
BOULE, P .
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 1991, 59 (02) :209-219
[2]   DETERMINATION OF KINETICS AND DIFFUSION-COEFFICIENTS OF METAL SORPTION ON CA-ALGINATE BEADS [J].
APEL, ML ;
TORMA, AE .
CANADIAN JOURNAL OF CHEMICAL ENGINEERING, 1993, 71 (04) :652-656
[3]   Cross-linking mechanisms of calcium and zinc in production of alginate microspheres [J].
Chan, LW ;
Jin, Y ;
Heng, PWS .
INTERNATIONAL JOURNAL OF PHARMACEUTICS, 2002, 242 (1-2) :255-258
[4]   DIFFUSIVITY OF CU2+ IN CALCIUM ALGINATE GEL BEADS [J].
CHEN, D ;
LEWANDOWSKI, Z ;
ROE, F ;
SURAPANENI, P .
BIOTECHNOLOGY AND BIOENGINEERING, 1993, 41 (07) :755-760
[5]   Equilibrium and kinetic studies of copper ion uptake by calcium alginate [J].
Chen, JP ;
Tendeyong, F ;
Yiacoumi, S .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 1997, 31 (05) :1433-1439
[6]   BIOLOGICAL INTERACTIONS BETWEEN POLYSACCHARIDES AND DIVALENT CATIONS - EGG-BOX MODEL [J].
GRANT, GT ;
MORRIS, ER ;
REES, DA ;
SMITH, PJC ;
THOM, D .
FEBS LETTERS, 1973, 32 (01) :195-198
[7]  
Gupta R, 2000, CURR SCI INDIA, V78, P967
[8]   DIFFUSIVITY OF CU2+ IN CALCIUM ALGINATE GEL BEADS [J].
JANG, LK .
BIOTECHNOLOGY AND BIOENGINEERING, 1994, 43 (02) :183-185
[9]   RECOVERY OF COPPER AND COBALT BY BIOPOLYMER GELS [J].
JANG, LK ;
LOPEZ, SL ;
EASTMAN, SL ;
PRYFOGLE, P .
BIOTECHNOLOGY AND BIOENGINEERING, 1991, 37 (03) :266-273
[10]   SELECTIVITY OF ALGINATE GEL FOR CU VS CO [J].
JANG, LK ;
NGUYEN, D ;
GEESEY, GG .
WATER RESEARCH, 1995, 29 (01) :307-313