The synergistic effect of attapulgite in the highly enhanced photoreduction of Cr(VI) by oxalic acid in aqueous solution

被引：23
作者：
Zhang, Ling [1 ]
Cao, Fengming [1 ]
Sun, Jie [1 ]
Sun, Yanqing [1 ]
机构：
[1] Shanghai Univ, Sch Environm & Chem Engn, Shanghai 200444, Peoples R China
来源：
ENVIRONMENTAL RESEARCH | 2021年 / 197卷
关键词：
Cr(VI) removal; Attapulgite; Oxalic acid; Photoreduction; Mechanism; PHOTOCATALYTIC REDUCTION; HEAVY-METALS; REMOVAL; CHROMIUM; CR(III); OXALATE; CLAY; NANOPARTICLES; POLYANILINE; ADSORPTION;
D O I：
10.1016/j.envres.2021.111070
中图分类号：
X [环境科学、安全科学];
学科分类号：
08 ; 0830 ;
摘要：
Attapulgite (ATP), a widely existed clay in nature, was firstly and successfully applied to enhance the photoreduction of highly toxic Cr(VI) by oxalic acid (Ox). In ATP + Ox + UV system, batch effects (Ox concentration, initial Cr(VI) concentration, ATP dosage, and reusability of ATP) were investigated. By studying the impact of the initial pH in the solution, the change of pH and Fe species concentration as well as Ox concentration during the reaction, the free radical scavenging test, and the role of ATP, the mechanism of Cr(VI) removal by ATP + Ox + UV system was revealed. The methyl orange (MO) removal of ATP + Ox + UV system was also inspected. The results indicated that ATP showed the obvious enhancement in efficient photoreduction of Cr(VI) by Ox in water. The Fe and Si components in ATP played an important role in Cr(VI) removal by ATP + Ox + UV system: most of Cr(VI) was reduced by Fe(II) and CO2 center dot- produced by the Fe(III)-Ox complex from the dissolved Fe component in ATP under UV irradiation. Some of Cr(VI) was reduced by e- and CO2 center dot- from the oxidation of Ox by h+ generated by the photocatalyzed SiO2 in ATP. Furthermore, ATP + Ox + UV system also showed excellent MO removal performance, indicating the great potential in practical applications.
引用
收藏
页数：9
相关论文
共 52 条
[21]   Covalent immobilization and characterization of penicillin G acylase on magnetic Fe2O3/Fe3O4 heterostructure nanoparticles prepared via a novel solution combustion and gel calcination process [J].
Liu, Ruijiang ;
Huang, Wei ;
Pan, Shuai ;
Li, You ;
Yu, Lulu ;
He, Dawei .
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES, 2020, 162 :1587-1596
[22]   Chemical and biological treatment technologies for leather tannery chemicals and wastewaters: A review [J].
Lofrano, Giusy ;
Meric, Sureyya ;
Zengin, Gulsum Emel ;
Orhon, Derin .
SCIENCE OF THE TOTAL ENVIRONMENT, 2013, 461 :265-281
[23]   Bioremediation of chromium solutions and chromium containing wastewaters [J].
Malaviya, Piyush ;
Singh, Asha .
CRITICAL REVIEWS IN MICROBIOLOGY, 2016, 42 (04) :607-633
[24]   As(III) and Cr(VI) oxyanion removal from water by advanced oxidation/reduction processesa review [J].
Marinho, Belisa A. ;
Cristovao, Raquel O. ;
Boaventura, Rui A. R. ;
Vilar, Vitor J. P. .
ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH, 2019, 26 (03) :2203-2227
[25]   Solar photocatalytic reduction of Cr(VI) over Fe(III) in the presence of organic sacrificial agents [J].
Marinho, Belisa A. ;
Cristovao, Raquel O. ;
Loureiro, Jose M. ;
Boaventura, Rui A. R. ;
Vilar, Vitor J. P. .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2016, 192 :208-219
[26]   Formation of Palygorskite Clay from Treated Diatomite and its Application for the Removal of Heavy Metals from Aqueous Solution [J].
Nefzi, Houwaida ;
Abderrabba, Manef ;
Ayadi, Sameh ;
Labidi, Jalel .
WATER, 2018, 10 (09)
[27]   The enhanced removal of highly toxic Cr(VI) by the synergy of uniform fiber ball loaded with Fe(OH)3 and oxalate acid [J].
Niu, Weiya ;
Sun, Jie ;
Zhang, Ling ;
Cao, Fengming .
CHEMOSPHERE, 2021, 262
[28]   Removal of uranium contaminant from aqueous solution by chitosan@attapulgite composite [J].
Pan, Duoqiang ;
Fan, Qiaohui ;
Fan, Fuyou ;
Tang, Yongfeng ;
Zhang, Yvying ;
Wu, Wangsuo .
SEPARATION AND PURIFICATION TECHNOLOGY, 2017, 177 :86-93
[29]   Thermodynamic analysis of the reactions of iron oxides: Dissolution oxalic acid [J].
Panias, D ;
Taxiarchou, M ;
Douni, I ;
Paspaliaris, I ;
Kontopoulos, A .
CANADIAN METALLURGICAL QUARTERLY, 1996, 35 (04) :363-373
[30]   Heavy metals removal from solution by palygorskite clay [J].
Potgieter, JH ;
Potgieter-Vermaak, SS ;
Kalibantonga, PD .
MINERALS ENGINEERING, 2006, 19 (05) :463-470
123456