Synthesis and Applications of Ferrocene-Fused Nitrogen Heterocycles

被引:19
作者
Bernardo, Olaya [1 ,2 ]
Gonzalez-Pelayo, Silvia [3 ]
Lopez, Luis A. [1 ,2 ]
机构
[1] Univ Oviedo, Dept Quim Organ & Inorgan, Inst Univ Quim Organometal Enrique Moles, Julian Claveria 8, Oviedo 33006, Spain
[2] Univ Oviedo, Ctr Innovac Quim Avanzada ORFEO CINQA, Julian Claveria 8, Oviedo 33006, Spain
[3] Univ Salamanca, Lab Quim Organ & Farmaceut, Dept Ciencias Farmaceut, Fac Farm, Campus Miguel de Unamuno, Salamanca 37007, Spain
关键词
Ferrocene; Nitrogen heterocycles; Fused ring systems; Planar chirality; Asymmetric catalysis; PLANAR CHIRAL FERROCENES; ENANTIOSELECTIVE NUCLEOPHILIC CATALYSIS; C-H ARYLATION; KINETIC RESOLUTION; ASYMMETRIC-SYNTHESIS; CRYSTALLOGRAPHIC CHARACTERIZATION; SECONDARY ALCOHOLS; BETA-LACTAMS; ACYLATION; 4-DIALKYLAMINOPYRIDINES;
D O I
10.1002/ejic.202100911
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The marriage of heterocyclic compounds with ferrocene has proven to be an extremely fruitful field of research. In fact, in the last years, several ferrocene-embedded heterocyclic compounds have been reported. In some cases, the synergistic combination of the properties of the heterocyclic and metallacyclic motifs provides to the fused systems interesting applications. This Review summarizes the major advances in the synthesis of ferrocene-fused nitrogen heterocyclic compounds and their applications, particularly in asymmetric catalysis.
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页数:12
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