Microwave-assisted synthesis and characterization of novel metal-free and metallophthalocyanines containing four 13-membered dithiadiaza macrocycles

被引:23
作者
Kantekin, Halit [1 ]
Biyikliglu, Zekeriya [1 ]
机构
[1] Karadeniz Tech Univ, Dept Chem, Fac Arts & Sci, TR-61080 Trabzon, Turkey
关键词
phthalocyanine; dithiadiazamacrocycle; phthalonitrile; macrocyclization; tosylation;
D O I
10.1016/j.dyepig.2007.03.012
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Novel, tetrasubstituted metal-free phthalocyanine and metallophtalocyanines bearing four 13-membered dithiadiaza. macrocycle peripheral groups were synthesized by cyclotetramerization of the phthalonitrile derivative in a multi-step reaction sequence, The new compounds were characterized by a combination of IR, H-1 NMR, C-13 NMR, UV-vis, elemental analysis and MS spectral data. (C) 2007 Elsevier Ltd. All rights reserved.
引用
收藏
页码:98 / 102
页数:5
相关论文
共 41 条
[1]   DICOPPER(II) CHLORO AND AZIDO INCLUSION COMPLEXES OF THE [24-ANE-N2S4] BINUCLEATING MACROCYCLE - SYNTHESIS, CRYSTAL AND MOLECULAR-STRUCTURES, AND SPECTRAL, MAGNETIC, AND ELECTROCHEMICAL PROPERTIES [J].
AGNUS, Y ;
LOUIS, R ;
GISSELBRECHT, JP ;
WEISS, R .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (01) :93-102
[2]  
[Anonymous], 1998, PHTHALOCYANINE MAT
[3]   Microwave assisted synthesis of substituted metallophthalocyanines and their catalytic activity in epoxidation reaction [J].
Bahadoran, F ;
Dialameh, S .
JOURNAL OF PORPHYRINS AND PHTHALOCYANINES, 2005, 9 (03) :163-169
[4]  
BIYIKLIOGLU Z, 2007, IN PRESS TRANSITION, DOI DOI 10.1007/S11243-007-0212-8
[5]   Microwave-assisted synthesis and characterization of novel metal-free and metallophthalocyanines containing four 14-membered tetraaza macrocycles [J].
Biyiklioglu, Zekeriya ;
Kantekin, Halit ;
Oezil, Musa .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2007, 692 (12) :2436-2440
[6]   SYNTHESIS AND CHARACTERIZATION OF SOME NOVEL PHTHALOCYANINES CONTAINING BOTH OLIGO(ETHYLENEOXY) AND ALKYL OR ALKOXY SIDE-CHAINS - NOVEL UNSYMMETRICAL DISCOTIC MESOGENS [J].
CLARKSON, GJ ;
MCKEOWN, NB ;
TREACHER, KE .
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1995, (14) :1817-1823
[7]   HEXAKIS(ALKYLTHIO)-SUBSTITUTED UNSYMMETRICAL PHTHALOCYANINES [J].
DABAK, S ;
GUL, A ;
BEKAROGLU, O .
CHEMISCHE BERICHTE-RECUEIL, 1994, 127 (10) :2009-2012
[8]   The synthesis and characterization of a novel (E,E)-dioxime and its mono, tri and pentanuclear complexes containing a nitrogen-sulfur mixed 15-membered macrocyclic moiety [J].
Gok, Y ;
Karabocek, S .
JOURNAL OF COORDINATION CHEMISTRY, 1996, 40 (03) :203-212
[9]  
Gürek AG, 1997, J PORPHYR PHTHALOCYA, V1, P227, DOI 10.1002/(SICI)1099-1409(199707)1:3<227::AID-JPP17>3.0.CO
[10]  
2-K