Gold and diazo reagents: a fruitful tool for developing molecular complexity

被引:125
作者
Fructos, Manuel R.
Mar Diaz-Requejo, M. [1 ,2 ]
Perez, Pedro J.
机构
[1] Univ Huelva, CIQSO Ctr Invest Quim Sostenible, Unidad Asociada CSIC, Lab Catalisis Homogenea, Campus El Carmen, Huelva 21007, Spain
[2] Univ Huelva, Dept Quim, Campus El Carmen, Huelva 21007, Spain
关键词
H BOND FUNCTIONALIZATION; CARBENE-TRANSFER-REACTIONS; CATALYTIC FUNCTIONALIZATION; CYCLOADDITION REACTIONS; ALPHA-DIAZOESTERS; CYCLOPROPANATION; ACTIVATION; REACTIVITY; INSERTION; OXIDES;
D O I
10.1039/c6cc01958g
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Since the discovery in 2005 of the potential of soluble Au complexes to catalyse the transfer of carbene groups from diazo compounds to organic substrates, an increasing number of transformations have been reported. In this contribution, the advances in the field are presented as foundations for further developments in the incoming years.
引用
收藏
页码:7326 / 7335
页数:10
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