Gold and diazo reagents: a fruitful tool for developing molecular complexity

被引：125

作者：

Fructos, Manuel R.

Mar Diaz-Requejo, M. ^{[1
,2
]}

Perez, Pedro J.

机构：

[1] Univ Huelva, CIQSO Ctr Invest Quim Sostenible, Unidad Asociada CSIC, Lab Catalisis Homogenea, Campus El Carmen, Huelva 21007, Spain

[2] Univ Huelva, Dept Quim, Campus El Carmen, Huelva 21007, Spain

来源：

CHEMICAL COMMUNICATIONS | 2016年 / 52卷 / 46期

关键词：

H BOND FUNCTIONALIZATION; CARBENE-TRANSFER-REACTIONS; CATALYTIC FUNCTIONALIZATION; CYCLOADDITION REACTIONS; ALPHA-DIAZOESTERS; CYCLOPROPANATION; ACTIVATION; REACTIVITY; INSERTION; OXIDES;

D O I：

10.1039/c6cc01958g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Since the discovery in 2005 of the potential of soluble Au complexes to catalyse the transfer of carbene groups from diazo compounds to organic substrates, an increasing number of transformations have been reported. In this contribution, the advances in the field are presented as foundations for further developments in the incoming years.

引用

页码：7326 / 7335

页数：10

共 88 条

[1]

[Anonymous], 1972, ADV INORG CHEM

[2] Reactivity of Stabilized Vinyl Diazo Derivatives toward Unsaturated Hydrocarbons: Regioselective Gold-Catalyzed Carbon-Carbon Bond Formation [J].

Barluenga, Jose ;

Lonzi, Giacomo ;

Tomas, Miguel ;

Lopez, Luis A. .

CHEMISTRY-A EUROPEAN JOURNAL, 2013, 19 (05) :1573-1576

[3]

Bhaduri S., 2014, Homogeneous catalysis: Mechanisms and industrial applications

[4] Enantioselective Gold(I)-Catalyzed Vinylogous [3+2] Cycloaddition between Vinyldiazoacetates and Enol Ethers [J].

Briones, John F. ;

Davies, Huw M. L. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2013, 135 (36) :13314-13317

[5] Gold(I)-Catalyzed Asymmetric Cyclopropenation of Internal Alkynes [J].

Briones, John F. ;

Davies, Huw M. L. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (29) :11916-11919

[6] Experimental evaluation of the electron donor ability of a gold phosphine fragment in a gold carbene complex [J].

Brooner, Rachel E. M. ;

Widenhoefer, Ross A. .

CHEMICAL COMMUNICATIONS, 2014, 50 (19) :2420-2423

[7] Catalytic functionalization of low reactive C(sp3)-H and C(sp2)-H bonds of alkanes and arenes by carbene transfer from diazo compounds [J].

Caballero, Ana ;

Diaz-Requejo, M. Mar ;

Fructos, Manuel R. ;

Olmos, Andrea ;

Urbano, Juan ;

Perez, Pedro J. .

DALTON TRANSACTIONS, 2015, 44 (47) :20295-20307

[8] Highly Stereoselective Olefin Cyclopropanation of Diazooxindoles Catalyzed by a C2-Symmetric Spiroketal Bisphosphine/Au(I) Complex [J].

Cao, Zhong-Yan ;

Wang, Xiaoming ;

Tan, Chen ;

Zhao, Xiao-Li ;

Zhou, Jian ;

Ding, Kuiling .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2013, 135 (22) :8197-8200

[9] A Desulfonylative Approach in Oxidative Gold Catalysis: Regiospecific Access to Donor-Substituted Acyl Gold Carbenes [J].

Chen, Hongyi ;

Zhang, Liming .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2015, 54 (40) :11775-11779

[10] Gold-Catalyzed Carbon-Heteroatom Bond-Forming Reactions [J].

Corma, A. ;

Leyva-Perez, A. ;

Sabater, Maria J. .

CHEMICAL REVIEWS, 2011, 111 (03) :1657-1712

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