Disposable electrospun electrodes based on conducting nanofibers

被引:16
作者
Granato, Flavio [1 ]
Scampicchio, Matteo [2 ]
Bianco, Andrea [1 ]
Mannino, Saverio [2 ]
Bertarelli, Chiara [1 ,3 ]
Zerbi, Giuseppe [1 ]
机构
[1] Univ Milan, Ctr Food Nanobiotechnol, I-20133 Milan, Italy
[2] Politecn Milan, Dept Chem Mat & Chem Engn, I-20133 Milan, Italy
[3] INSTM, I-50121 Florence, Italy
关键词
conducting nanofibers; electrospun electrodes; nylon-6; ferric chloride fibers;
D O I
10.1002/elan.200804185
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
A new approach for the fabrication of disposable electrochemical surfaces is presented. Conducting fibers have been produced by a two-step process. Firstly, a fine web mat composed of nylon-6 and ferric chloride fibers (with diameters of about 200 nm) were electrospun on a flat collector. Afterwards, the electrospun mat was exposed to pyrrole vapor under controlled dry atmosphere until each nylon thread was fully coated with a conducting polypyrrole layer. The conducting fiber mat was finally integrated within an electrochemical cell and used as a disposable sensor device. The suitability of the sensor was tested using phosphate and carbonate organic anions. The large scale fabrication of conducting tissue, in the form of a fine web of spun nanofibers, is relatively fast and inexpensive, and it paves the way to the build up of new disposable electrodes.
引用
收藏
页码:1374 / 1377
页数:4
相关论文
共 14 条
[1]   Polymers in sensor applications [J].
Adhikari, B ;
Majumdar, S .
PROGRESS IN POLYMER SCIENCE, 2004, 29 (07) :699-766
[2]   Strong orientation of polymer chains and small photochromic molecules in polyamide 6 electrospun fibers [J].
Bianco, Andrea ;
Iardino, Giacomo ;
Manuelli, Alessandro ;
Bertarelli, Chiara ;
Zerbi, Giuseppe .
CHEMPHYSCHEM, 2007, 8 (04) :510-514
[3]   AN IR SPECTROSCOPIC STUDY OF THE ELECTROCHEMICAL REDUCTION OF POLYPYRROLE DOPED WITH DODECYL-SULFATE ANION [J].
DAVIDSON, RG ;
TURNER, TG .
SYNTHETIC METALS, 1995, 72 (02) :121-128
[4]   Application of conducting polymers to biosensors [J].
Gerard, M ;
Chaubey, A ;
Malhotra, BD .
BIOSENSORS & BIOELECTRONICS, 2002, 17 (05) :345-359
[5]   Electrospinning: A fascinating method for the preparation of ultrathin fibres [J].
Greiner, Andreas ;
Wendorff, Joachim H. .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (30) :5670-5703
[6]   POLYPYRROLE ELECTRODE AS A DETECTOR FOR ELECTROINACTIVE ANIONS BY FLOW-INJECTION ANALYSIS [J].
IKARIYAMA, Y ;
HEINEMAN, WR .
ANALYTICAL CHEMISTRY, 1986, 58 (08) :1803-1806
[8]   Metal/conducting-polymer composite nanowires [J].
Meenach, Samantha A. ;
Burdick, Jared ;
Kunwar, Anurag ;
Wang, Joseph .
SMALL, 2007, 3 (02) :239-243
[9]   New materials for electrochemical sensing VI:: Carbon nanotubes [J].
Merkoçi, A ;
Pumera, M ;
Llopis, X ;
Pérez, B ;
del Valle, M ;
Alegret, S .
TRAC-TRENDS IN ANALYTICAL CHEMISTRY, 2005, 24 (09) :826-838
[10]   Amperometric ion sensing using polypyrrole membranes [J].
Michalska, A ;
Walkiewicz, S ;
Maksymiuk, K .
ELECTROANALYSIS, 2003, 15 (5-6) :509-517