Synthesis, x-ray crystal structure and bonding in [(PPh(3))(2)PtSe](2)

被引：31
|
作者：
Bencini, A
diVaira, M
Morassi, R
Stoppioni, P
Mele, F
机构：
[1] UNIV FLORENCE, DIPARTIMENTO CHIM, I-50144 FLORENCE, ITALY
[2] UNIV CALABRIA, DIPARTIMENTO CHIM, I-87030 ARCAVACATA, ITALY
来源：
POLYHEDRON | 1996年 / 15卷 / 12期
关键词：
D O I：
10.1016/0277-5387(95)00441-6
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The compound [(PPh(3))(2)PtSe](2) has been obtained by reacting a selenide solution with (PPh(3))(2)PtCl2 and its structure has been determined by X-ray diffraction analysis. The molecular geometry of the complex consists of a four membered Pt2Se2 ring with two triphenylphosphine ligands coordinated to each platinum, giving a planar (P2Pt)(2)Se-2 arrangement. MO calculations have shown that the planar geometry is indeed slightly favoured for the neutral compound but anticipate a bent geometry for a hypothetical cationic species, in agreement with what has been found for related tellurium derivatives.
引用
收藏
页码：2079 / 2086
页数：8
相关论文
共 50 条
  • [1] SYNTHESIS AND X-RAY CRYSTAL-STRUCTURE OF A NOVEL IRON NITROSYL COMPLEX, FE(NO)(2)PPH(3)(ETA(2)-TCNE)
    LI, LJ
    ENRIGHT, GD
    PRESTON, KF
    ORGANOMETALLICS, 1994, 13 (12) : 4686 - 4688
  • [2] The isolation and x-ray crystal structure of [Li(Et(2)O)(2)(CHPh)PPh(2)]
    Decken, A
    Cowley, AH
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1996, 509 (02) : 135 - 137
  • [3] Synthesis and X-ray crystal structure of the heterobimetallic complex [FeRh(μ-CO)(CO)3μ-PBut2(μ-Ph 2PCH2PPh2)]
    Inst. für Anorganische Chemie, Martin-Luther-Univ. Halle-Wittenberg, Kurt-Mothes-Str. 2, D-06120 Halle, Germany
    Z. Naturforsch. Sect. B J. Chem. Sci., 7 (810-814):
  • [4] X-RAY CRYSTAL-STRUCTURE AND BONDING IN CL2SI(BIPYRIDYL)2
    MACDIARMID, AG
    CHU, J
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1975, (169): : 75 - 75
  • [5] METALLACYCLOHEXATRIENES OR METALLABENZENES - SYNTHESIS OF OSMABENZENE DERIVATIVES AND X-RAY CRYSTAL-STRUCTURE OF [OS(CSCHCHCHCH)(CO)(PPH3)2]
    ELLIOTT, GP
    ROPER, WR
    WATERS, JM
    JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1982, (14) : 811 - 813
  • [6] Synthesis and X-ray crystal structure of [Me2GaBi(SiMe3)2]3
    Thomas, F
    Schulz, S
    Nieger, M
    ORGANOMETALLICS, 2002, 21 (13) : 2793 - 2795
  • [7] The isolation and X-ray crystal structure of [Li(Et2O)2(CHPh)PPh2]
    J Organomet Chem, 2 (135):
  • [8] SYNTHESIS AND X-RAY CRYSTAL-STRUCTURE OF 2 TRIORGANOSTANNYLCOBALT COMPLEXES
    GIELEN, M
    VANDENEYNDE, I
    POLET, F
    MEUNIERPIRET, J
    VANMEERSSCHE, M
    BULLETIN DES SOCIETES CHIMIQUES BELGES, 1980, 89 (10): : 915 - 927
  • [9] X-RAY CRYSTAL-STRUCTURE DETERMINATION OF (PHCOO)2(PPH3)2(CO)2RU - STEREOCHEMISTRY ASSIGNMENTS
    ROTEM, M
    STEIN, Z
    SHVO, Y
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1990, 387 (01) : 95 - 101
  • [10] SYNTHESIS AND X-RAY STRUCTURE OF [REBR3(NNPH)(PPH3)2], A PARAMAGNETIC ORGANODIAZENIDO COMPLEX
    RIBEIRO, MTA
    POMBEIRO, AJL
    DILWORTH, JR
    ZHENG, YF
    MILLER, JR
    INORGANICA CHIMICA ACTA, 1993, 211 (02) : 131 - 132
12345