Trip2C6H3SeF: The First Isolated Selenenyl Fluoride

被引：21

作者：

Poleschner, Helmut ^{[1
]}

Ellrodt, Stefan ^{[1
]}

Malischewski, Moritz ^{[1
]}

Nakatsuji, Jun-ya ^{[2
]}

Rohner, Christian ^{[3
]}

Seppelt, Konrad ^{[1
]}

机构：

[1] Free Univ Berlin, Inst Chem & Biochem Anorgan & Analyt Chem, D-14195 Berlin, Germany

[2] Hiroshima Univ, Dept Chem, Grad Sch Sci, Higashihiroshima 7398526, Japan

[3] Univ Giessen, Inst Anorgan & Analyt Chem, D-35392 Giessen, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2012年 / 51卷 / 02期

关键词：

ab initio calculations; fluorine; selenium; structure elucidation; tellurium; DIFLUORIDE-DIORGANYL DISELENIDES; LOWER CHALCOGEN FLUORIDES; SE-NITROSOSELENOL; METAL DERIVATIVES; F EQUIVALENTS; M-TERPHENYLS; FLUOROSELENENYLATION; DITELLURIDE; ACETYLENES; CHEMISTRY;

D O I：

10.1002/anie.201106708

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Joining the stable: The first examples of the highly instable selenenyl fluorides RSeF are prepared from the reaction on the tin selenide RSeSnMe 3 with XeF 2. Through the use of extremely large protecting groups (m-terphenyl ligands) which stabilizes the RSeF units against disproportionation, the compounds could be isolated and characterized by NMR spectroscopy and single-crystal structure analysis (see structure). Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：419 / 422

页数：4

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