Trip2C6H3SeF: The First Isolated Selenenyl Fluoride

被引：21
|
作者：
Poleschner, Helmut [1 ]
Ellrodt, Stefan [1 ]
Malischewski, Moritz [1 ]
Nakatsuji, Jun-ya [2 ]
Rohner, Christian [3 ]
Seppelt, Konrad [1 ]
机构：
[1] Free Univ Berlin, Inst Chem & Biochem Anorgan & Analyt Chem, D-14195 Berlin, Germany
[2] Hiroshima Univ, Dept Chem, Grad Sch Sci, Higashihiroshima 7398526, Japan
[3] Univ Giessen, Inst Anorgan & Analyt Chem, D-35392 Giessen, Germany
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2012年 / 51卷 / 02期
关键词：
ab initio calculations; fluorine; selenium; structure elucidation; tellurium; DIFLUORIDE-DIORGANYL DISELENIDES; LOWER CHALCOGEN FLUORIDES; SE-NITROSOSELENOL; METAL DERIVATIVES; F EQUIVALENTS; M-TERPHENYLS; FLUOROSELENENYLATION; DITELLURIDE; ACETYLENES; CHEMISTRY;
D O I：
10.1002/anie.201106708
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Joining the stable: The first examples of the highly instable selenenyl fluorides RSeF are prepared from the reaction on the tin selenide RSeSnMe 3 with XeF 2. Through the use of extremely large protecting groups (m-terphenyl ligands) which stabilizes the RSeF units against disproportionation, the compounds could be isolated and characterized by NMR spectroscopy and single-crystal structure analysis (see structure). Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：419 / 422
页数：4
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