Formation of metallofullerenes with higher group elements

被引:27
作者
Sueki, K
Kikuchi, K
Akiyama, K
Sawa, T
Katada, M
Ambe, S
Ambe, F
Nakahara, H
机构
[1] Tokyo Metropolitan Univ, Grad Sch Sci, Dept Chem, Tokyo 1920397, Japan
[2] RIKEN, Inst Phys & Chem Res, Wako, Saitama 3510198, Japan
关键词
D O I
10.1016/S0009-2614(98)01353-0
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The formation of metallofullerenes was examined for 23 elements, and some experimental evidence was obtained for metallofullerenes with group-4, Zr and Hf, and group-5, Nb, elements. Relative yields of the metallofullerenes eluted at the retention time around those for M@C-82 (M = group-2, and -3 elements) were found to decrease exponentially as the group number increased. The yields for Fe and Co, namely group-8 and -9 elements, were estimated to be less than one hundredth of that for M@C-82 (M = lanthanoid) (C) 1999 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:140 / 144
页数:5
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