Gas-phase kinetic and theoretical studies of reactions of germylenes and dimethylstannylene

被引：35
|
作者：
Boganov, SE
Egorov, MP
Faustov, VI
Krylova, LV
Nefedov, OM
Becerra, R
Walsh, R
机构：
[1] Russian Acad Sci, ND Zelinskii Organ Chem Inst, Moscow 119991, Russia
[2] CSIC, Inst Quim Fis Rocasolano, E-28006 Madrid, Spain
[3] Univ Reading, Dept Chem, Reading RG6 6AD, Berks, England
来源：
RUSSIAN CHEMICAL BULLETIN | 2005年 / 54卷 / 03期
关键词：
germylene; dimethylgermylene; dimethylstannylene; reaction kinetics; time-resolved; studies; quantum-chemical calculations; RRKM calculations; Arrhenius parameters; thermochemistry;
D O I：
10.1007/s11172-005-0285-5
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The results of time-resolved gas phase studies of labile germylenes (GeH2 and GeMe2) and dimethylstannylene (SnMe2) reactions reported to date are considered together with data of quantum-chemical investigations of the potential energy surfaces of these systems. Reaction mechanisms are discussed. A comparison of reactivity in the series of carbene analogs, ER2 (E = Si, Ge, Sn, R = H, Me), is made.
引用
收藏
页码：483 / 511
页数：29
相关论文
共 50 条
  • [1] Gas phase kinetic and theoretical studies of reactions of germylenes and dimethylstannylene
    S. E. Boganov
    M. P. Egorov
    V. I. Faustov
    I. V. Krylov
    O. M. Nefedov
    R. Becerra
    R. Walsh
    Russian Chemical Bulletin, 2005, 54 : 483 - 511
  • [2] Kinetic parameters for gas-phase reactions: Experimental and theoretical challenges
    Carl, S. A.
    Vereecken, L.
    Peeters, J.
    PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2007, 9 (31) : 4071 - 4084
  • [3] Reactions of silylene with unreactive molecules. 2. Nitrogen: Gas-phase kinetic and theoretical studies
    Becerra, R
    Cannady, JP
    Walsh, R
    JOURNAL OF PHYSICAL CHEMISTRY A, 2003, 107 (45): : 9588 - 9593
  • [4] Reactions of silylene with unreactive molecules. I: Carbon dioxide; Gas-phase kinetic and theoretical studies
    Becerra, R
    Cannady, JP
    Walsh, R
    JOURNAL OF PHYSICAL CHEMISTRY A, 2002, 106 (19): : 4922 - 4927
  • [5] Reaction of Germylene with Sulfur Dioxide: Gas-Phase Kinetic and Theoretical Studies
    Becerra, Rosa
    Cannady, J. Pat
    Walsh, Robin
    ORGANOMETALLICS, 2014, 33 (22) : 6493 - 6503
  • [6] Multichannel Gas-Phase Unimolecular Decomposition of Acetone: Theoretical Kinetic Studies
    Saheb, Vahid
    Zokaie, Meymanat
    JOURNAL OF PHYSICAL CHEMISTRY A, 2018, 122 (28): : 5895 - 5904
  • [7] Theoretical studies on gas-phase reactions of negative ions with alkyl nitrites
    Park, HY
    Kim, CK
    Lee, BS
    Lee, HW
    Lee, I
    BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 2000, 21 (08) : 823 - 827
  • [8] First gas-phase detection of dimethylstannylene and time-resolved study of some of its reactions
    Becerra, R
    Boganov, SE
    Egorov, MP
    Faustov, VI
    Krylova, IV
    Nefedov, OM
    Walsh, R
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (25) : 7555 - 7562
  • [9] Reaction of silylene with sulfur dioxide: some gas-phase kinetic and theoretical studies
    Becerra, Rosa
    Cannady, J. Pat
    Goldberg, Nicola
    Walsh, Robin
    PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2013, 15 (35) : 14748 - 14760
  • [10] KINETIC-STUDIES OF GAS-PHASE ATMOSPHERIC OXIDATION REACTIONS OF DIMETHYL SULFIDE
    MARTIN, D
    JOURDAIN, JL
    LAVERDET, G
    LEBRAS, G
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1987, 194 : 146 - ENVR
12345