Direct, copper-catalyzed oxidation of aromatic C-H bonds with hydrogen peroxide under acid-free conditions

被引：60

作者：

Conde, Ana ^{[1
]}

Mar Diaz-Requejo, M. ^{[1
]}

Perez, Pedro J. ^{[1
]}

机构：

[1] Univ Huelva, Lab Catalisis Homogenea, Ctr Invest Quim Sostenible CIQSO, Dept Quim & Ciencia Mat,Unidad Asociada,CSIC, Huelva 21007, Spain

来源：

CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 28期

关键词：

ORGANIC-COMPOUNDS; BENZENE; PHENOL; HYDROXYLATION; CONVERSION; EPOXIDATION; ACTIVATION; COMPLEXES; SYSTEM; H2O2;

D O I：

10.1039/c1cc12804c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The direct oxidation of benzene into phenol using hydrogen peroxide has been achieved in the absence of any acid with Tp(x)Cu(NCMe) complexes as the catalysts. In the case of anthracenes as the substrates, valuable anthraquinones have been quantitatively obtained in the same manner.

引用

页码：8154 / 8156

页数：3

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